Comparison of ICP OES and LIBS Analysis of Medicinal Herbs Rich in Flavonoids from Eastern Europe

被引：35
作者：
Andrade, Daniel F. [1 ]
Pereira-Filho, Edenir Rodrigues [1 ]
Konieczynski, Pawel [2 ]
机构：
[1] Univ Fed Sao Carlos UFSCar, GAIA, DQ, CCET, POB 676, BR-13565905 Sao Carlos, SP, Brazil
[2] Med Univ Gdansk, Dept Analyt Chem, Gen J Hallera 107, PL-80416 Gdansk, Poland
来源：
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2017年 / 28卷 / 05期
关键词：
medicinal herbs; essential and toxic metals; LIBS; ICP OES; chemometrics; INDUCED BREAKDOWN SPECTROSCOPY; PRINCIPAL COMPONENT ANALYSIS; TRACE-ELEMENTS; NEUTRON-ACTIVATION; INFUSIONS; INFORMATION; FINGERPRINT; CALCIUM; PLANTS; HONEY;
D O I：
10.21577/0103-5053.20160236
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Essential and toxic metals were determined in eighteen samples of medicinal herbs from Poland, Lithuania and Serbia by means of laser-induced breakdown spectroscopy (LIBS) and inductively coupled plasma optical emission spectrometry (ICP OES). Calcium, K and Mg concentrations were obtained in % (m/m) and other metals (Na, Co, Cu, Fe, Mn, Ni, Zn, Cd, Cr and Pb) in mg kg-1. The fact that the herb samples analyzed belonged to specific plant species and represented different morphological plant parts explained the characteristic distribution in two-dimensional scores plots obtained by principal component analysis (PCA). A strong correlation of LIBS results was achieved in comparison to those obtained by ICP OES for Ca, K and Mg. Differences in the types of infusions were observed, in that leaves are related to Zn and Ni concentrations, leaves and flowers to Co, Ca and Mn concentrations and flowers to K, Na, Mg and Fe content.
引用
收藏
页码：838 / 847
页数：10
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  • [1] The potential of laser-induced breakdown spectroscopy for industrial at-line monitoring of calcium content in comminuted poultry meat
    Andersen, Maj-Britt Schmidt
    Frydenvang, Jens
    Henckel, Poul
    Rinnan, Asmund
    [J]. FOOD CONTROL, 2016, 64 : 226 - 233
  • [2] Obtaining information about valuable metals in computer and mobile phone scraps using laser-induced breakdown spectroscopy (LIBS)
    Aquino, Francisco W. B.
    Santos, Jozemir M.
    Carvalho, Rodrigo R. V.
    Coelho, Jomarc A. O.
    Pereira-Filho, Edenir R.
    [J]. RSC ADVANCES, 2015, 5 (82) : 67001 - 67010
  • [3] Analysis of the polymeric fractions of scrap from mobile phones using laser-induced breakdown spectroscopy: Chemometric applications for better data interpretation
    Aquino, Francisco W. B.
    Pereira-Filho, Edenir R.
    [J]. TALANTA, 2015, 134 : 65 - 73
  • [4] Identification of diversity in elements content in medicinal plants belonging to different plant families
    Arceusz, Agnieszka
    Radecka, Iwona
    Wesolowski, Marek
    [J]. FOOD CHEMISTRY, 2010, 120 (01) : 52 - 58
  • [5] Plastic identification based on molecular and elemental information from laser induced breakdown spectra: a comparison of plasma conditions in view of efficient sorting
    Barbier, Sophie
    Perrier, Sebastien
    Freyermuth, Pierre
    Perrin, Didier
    Gallard, Benjamin
    Gilon, Nicole
    [J]. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2013, 88 : 167 - 173
  • [6] Determination of mineral and trace elements in some medicinal herbs and their infusions consumed in Turkey
    Basgel, S
    Erdemoglu, SB
    [J]. SCIENCE OF THE TOTAL ENVIRONMENT, 2006, 359 (1-3) : 82 - 89
  • [7] Development of a mobile system based on laser-induced breakdown spectroscopy and dedicated to in situ analysis of polluted soils
    Bousquet, B.
    Travaille, G.
    Ismael, A.
    Canioni, L.
    Pierres, K. Michel-Le
    Brasseur, E.
    Roy, S.
    le Hecho, I.
    Larregieu, M.
    Tellier, S.
    Potin-Gauder, M.
    Boriachon, T.
    Wazen, P.
    Diard, A.
    Belbeze, S.
    [J]. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2008, 63 (10) : 1085 - 1090
  • [8] Laser-induced breakdown spectroscopy (LIBS) combined with hyperspectral imaging for the evaluation of printed circuit board composition
    Carvalho, Rodrigo R. V.
    Coelho, Jomarc A. O.
    Santos, Jozemir M.
    Aquino, Francisco W. B.
    Carneiro, Renato L.
    Pereira-Filho, Edenir R.
    [J]. TALANTA, 2015, 134 : 278 - 283
  • [9] Twelve different types of data normalization for the proposition of classification, univariate and multivariate regression models for the direct analyses of alloys by laser-induced breakdown spectroscopy (LIBS)
    Castro, Jeyne Pricylla
    Pereira-Filho, Edenir Rodrigues
    [J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2016, 31 (10) : 2005 - 2014
  • [10] Laser-Induced Breakdown Spectroscopy-Capabilities and Limitations
    Cremers, David A.
    Chinni, Rosemarie C.
    [J]. APPLIED SPECTROSCOPY REVIEWS, 2009, 44 (06) : 457 - 506
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