Direct Conversion of 5-Hydroxymethylfurfural to Furanic Diether by Copper-Loaded Hierarchically Structured ZSM-5 Catalyst in a Fixed-Bed Reactor

被引：13

作者：

Hu, Hualei ^{[1
]}

Xue, Tingting ^{[1
,2
]}

Zhang, Zhenxin ^{[1
,3
]}

Gan, Jiang ^{[1
,3
]}

Chen, Liangqi ^{[1
,2
]}

Zhang, Jian ^{[1
,3
]}

Qu, Fengzuo ^{[2
]}

Cai, Weijie ^{[2
]}

Wang, Lei ^{[1
,4
]}

机构：

[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Peoples R China

[2] Dalian Polytech Univ, 1st Qinggongyuan, Dalian 116034, Peoples R China

[3] Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China

[4] Zhejiang Sugar Energy Technol Co Ltd, 1818 Zhongguan West Rd, Ningbo 315201, Peoples R China

来源：

CHEMCATCHEM | 2021年 / 13卷 / 15期

关键词：

5-Hydroxymethylfurfural; Hydrogenation; Etherification; 2; 5-Bis(ethoxymethyl)furan; Bifunctional catalyst; TRANSFER HYDROGENATION; REDUCTIVE ETHERIFICATION; SELECTIVE HYDROGENATION; CU/AL2O3; CATALYSTS; EFFICIENT; ZEOLITE; ACID; LEWIS; 2,5-BIS(HYDROXYMETHYL)FURAN; PERFORMANCE;

D O I：

10.1002/cctc.202100489

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The highly-efficient conversion of 5-hydroxymethylfurfural (HMF) to 2,5-bis(ethoxymethyl)furan (BEMF) was achieved over the copper-loaded hierarchically structured ZSM-5 (Cu/HSZ) catalysts in the continuous fixed-bed reactor. The main reaction path for BEMF synthesis on the Cu/HSZ catalysts was confirmed as following: HMF was firstly hydrogenated to BHMF intermediates over metal sites and then the formed BHMF was etherified by acid sites. Benefiting from the ammonia evaporation (AE) method promoted the dispersion of copper and reduced the acidity, the Cu/HSZ-AE catalyst exhibited more excellent BEMF yield and stability than the catalyst prepared by conventional incipient-wetness impregnation (Cu/HSZ-IW). Indeed, the inactivation of Cu/HSZ-IW catalyst was mainly attributed to the deactivation of copper by carbon species deposition.

引用

页码：3461 / 3469

页数：9

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