Hypervalent Iodine as a Terminal Oxidant in Wacker-Type Oxidation of Terminal Olefins to Methyl Ketones

被引：53

作者：

Chaudhari, Dipali A. ^{[1
]}

Fernandes, Rodney A. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 81卷 / 05期

关键词：

SUPERCRITICAL CARBON-DIOXIDE; DESS-MARTIN PERIODINANE; PALLADIUM-CATALYZED OXIDATION; PROTECTED ALLYLIC AMINES; SELECTIVE OXIDATION; AEROBIC OXIDATION; SECONDARY ALCOHOLS; MOLECULAR-OXYGEN; SOLE OXIDANT; EFFICIENT;

D O I：

10.1021/acs.joc.6b00137

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mimic of the Wacker process for C=O bond formation in terminal olefins can be initiated by a combination of the Pd(II) and hypervalent iodine reagent, Dess-Martin periodinane to generate methyl ketones. This operationally simple and scalable method offers Markovnikov selectivity, has good functional group compatibility, and is mild and high yielding.

引用

页码：2113 / 2121

页数：9

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