A Highly Selective and Turn-on Fluorescence Sensor for Detection of Cyanide

被引:19
作者
Jhong, Yi [1 ]
Hsieh, Wei Hsun [1 ]
Chir, Jiun-Ly [1 ]
Wu, An-Tai [1 ]
机构
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
关键词
Chemosensor; Fluorescence; Turn-on; Cyanide; ANION-BINDING; PROBE; RECOGNITION; WATER;
D O I
10.1007/s10895-014-1460-6
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
2-Hydroxy-1-naphthaldehyde (receptor 1) serves as a selective chemosensor for cyanide anion (CN-). In the presence of CN-, an enhanced fluorescent intensity and red shift were observed. The observed complexation between receptor 1 and CN- may cause from a formation of phenoxide anion by nucleophilic addition of the CN- to carbonyl group.
引用
收藏
页码:1723 / 1726
页数:4
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