We demonstrate how the matrix-valued mode-coupling theory of the glass transition and glassy dynamics in planar confinement converges to the corresponding theory for two-dimensional (2D) planar and the three-dimensional bulk liquid, provided the wall potential satisfies certain conditions. Since the mode-coupling theory relies on the static properties as input, the emergence of a homogeneous limit for the matrix-valued intermediate scattering functions is directly connected to the convergence of the corresponding static quantities to their conventional counterparts. We show that the 2D limit is more subtle than the bulk limit, in particular, the in-planar dynamics decouples from the motion perpendicular to the walls. We investigate the frozen-in parts of the intermediate scattering function in the glass state and find that the limits time t -> infinity and effective wall separation L -> 0 do not commute due to the mutual coupling of the residual transversal and lateral force kernels.
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Natl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USANatl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USA
Douglas, Jack F.
Prabhu, Vivek M.
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Natl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USANatl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USA
Prabhu, Vivek M.
Ma, Yuanchi
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Natl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USANatl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USA
Ma, Yuanchi
Hudson, Steven D.
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Natl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USANatl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USA
Hudson, Steven D.
Salipante, Paul F.
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Natl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USANatl Inst Stand & Technol, Mat Sci & Engn Div, Mat Measurement Lab, Gaithersburg, MD 20899 USA
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Donostia Int Phys Ctr, E-20018 San Sebastian, SpainUniv Basque Country, CSIC, Ctr Fis Mat, E-20018 San Sebastian, Spain
Bernabei, Marco
Moreno, Angel J.
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Univ Basque Country, CSIC, Ctr Fis Mat, E-20018 San Sebastian, Spain
Mat Phys Ctr MPC, E-20018 San Sebastian, SpainUniv Basque Country, CSIC, Ctr Fis Mat, E-20018 San Sebastian, Spain
Moreno, Angel J.
Zaccarelli, Emanuela
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Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
Univ Roma La Sapienza, CNR ISC, I-00185 Rome, ItalyUniv Basque Country, CSIC, Ctr Fis Mat, E-20018 San Sebastian, Spain
Zaccarelli, Emanuela
Sciortino, Francesco
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Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
Univ Roma La Sapienza, CNR ISC, I-00185 Rome, ItalyUniv Basque Country, CSIC, Ctr Fis Mat, E-20018 San Sebastian, Spain
Sciortino, Francesco
Colmenero, Juan
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Univ Basque Country, CSIC, Ctr Fis Mat, E-20018 San Sebastian, Spain
Mat Phys Ctr MPC, E-20018 San Sebastian, Spain
Donostia Int Phys Ctr, E-20018 San Sebastian, Spain
Univ Basque Country, Dept Fis Mat, E-20080 San Sebastian, SpainUniv Basque Country, CSIC, Ctr Fis Mat, E-20018 San Sebastian, Spain