Glassy dynamics in confinement: Planar and bulk limits of the mode-coupling theory

被引:14
|
作者
Lang, Simon [1 ]
Schilling, Rolf [2 ]
Franosch, Thomas [1 ]
机构
[1] Leopold Franzens Univ Innsbruck, Inst Theoret Phys, A-6020 Innsbruck, Austria
[2] Johannes Gutenberg Univ Mainz, Inst Phys, D-55099 Mainz, Germany
来源
PHYSICAL REVIEW E | 2014年 / 90卷 / 06期
关键词
INTERMEDIATE SCATTERING FUNCTION; HARD-SPHERES; 2; DIMENSIONS; TRANSITION; LIQUIDS; FORMER; FLUIDS;
D O I
10.1103/PhysRevE.90.062126
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We demonstrate how the matrix-valued mode-coupling theory of the glass transition and glassy dynamics in planar confinement converges to the corresponding theory for two-dimensional (2D) planar and the three-dimensional bulk liquid, provided the wall potential satisfies certain conditions. Since the mode-coupling theory relies on the static properties as input, the emergence of a homogeneous limit for the matrix-valued intermediate scattering functions is directly connected to the convergence of the corresponding static quantities to their conventional counterparts. We show that the 2D limit is more subtle than the bulk limit, in particular, the in-planar dynamics decouples from the motion perpendicular to the walls. We investigate the frozen-in parts of the intermediate scattering function in the glass state and find that the limits time t -> infinity and effective wall separation L -> 0 do not commute due to the mutual coupling of the residual transversal and lateral force kernels.
引用
收藏
页数:10
相关论文
共 38 条
  • [31] Size dependence of transport coefficients of thin and long asphaltene molecules as determined using a mode-coupling theory approach
    Wong, Chi Pui Jeremy
    Choi, Phillip
    PHYSICS OF FLUIDS, 2024, 36 (09)
  • [32] A crucial role of long-range hydrodynamic interactions near the colloidal glass transition based on time-convolutionless mode-coupling theory
    Tokuyama, Michio
    Narumi, Takayuki
    Kawamura, Junichi
    PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2018, 512 : 552 - 565
  • [33] On the relation between a length cutoff in time-convolutionless mode-coupling theory and a characteristic length at β-relaxation stage in glass-forming materials
    Tokuyama, Michio
    Narumi, Takayuki
    PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2019, 514 : 533 - 548
  • [34] Nonlinear response of dense colloidal suspensions under oscillatory shear: Mode-coupling theory and Fourier transform rheology experiments
    Brader, J. M.
    Siebenbuerger, M.
    Ballauff, M.
    Reinheimer, K.
    Wilhelm, M.
    Frey, S. J.
    Weysser, F.
    Fuchs, M.
    PHYSICAL REVIEW E, 2010, 82 (06):
  • [35] Applicability of the Generalized Stokes-Einstein Equation of Mode-Coupling Theory to Near-Critical Polyelectrolyte Complex Solutions
    Douglas, Jack F.
    Prabhu, Vivek M.
    Ma, Yuanchi
    Hudson, Steven D.
    Salipante, Paul F.
    ACS MACRO LETTERS, 2023, 12 (02) : 288 - 294
  • [36] Simulated glass-forming polymer melts: Dynamic scattering functions, chain length effects, and mode-coupling theory analysis
    Frey, S.
    Weysser, F.
    Meyer, H.
    Farago, J.
    Fuchs, M.
    Baschnagel, J.
    EUROPEAN PHYSICAL JOURNAL E, 2015, 38 (02) : 1 - 18
  • [37] Zero shear viscosity of two polyatomic glass-forming liquids calculated by Vogel-Fulcher law and schematic mode-coupling theory
    Wong, Chi Pui Jeremy
    Choi, Phillip
    PHYSICS OF FLUIDS, 2024, 36 (03)
  • [38] From caging to Rouse dynamics in polymer melts with intramolecular barriers: A critical test of the mode coupling theory
    Bernabei, Marco
    Moreno, Angel J.
    Zaccarelli, Emanuela
    Sciortino, Francesco
    Colmenero, Juan
    JOURNAL OF CHEMICAL PHYSICS, 2011, 134 (02)