Glassy dynamics in confinement: Planar and bulk limits of the mode-coupling theory

被引:14
|
作者
Lang, Simon [1 ]
Schilling, Rolf [2 ]
Franosch, Thomas [1 ]
机构
[1] Leopold Franzens Univ Innsbruck, Inst Theoret Phys, A-6020 Innsbruck, Austria
[2] Johannes Gutenberg Univ Mainz, Inst Phys, D-55099 Mainz, Germany
来源
PHYSICAL REVIEW E | 2014年 / 90卷 / 06期
关键词
INTERMEDIATE SCATTERING FUNCTION; HARD-SPHERES; 2; DIMENSIONS; TRANSITION; LIQUIDS; FORMER; FLUIDS;
D O I
10.1103/PhysRevE.90.062126
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We demonstrate how the matrix-valued mode-coupling theory of the glass transition and glassy dynamics in planar confinement converges to the corresponding theory for two-dimensional (2D) planar and the three-dimensional bulk liquid, provided the wall potential satisfies certain conditions. Since the mode-coupling theory relies on the static properties as input, the emergence of a homogeneous limit for the matrix-valued intermediate scattering functions is directly connected to the convergence of the corresponding static quantities to their conventional counterparts. We show that the 2D limit is more subtle than the bulk limit, in particular, the in-planar dynamics decouples from the motion perpendicular to the walls. We investigate the frozen-in parts of the intermediate scattering function in the glass state and find that the limits time t -> infinity and effective wall separation L -> 0 do not commute due to the mutual coupling of the residual transversal and lateral force kernels.
引用
收藏
页数:10
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