Effects of controlled anodic treatments on electrochemical behaviour of boron doped diamond

被引：31

作者：

Girard, H. A. ^{[1
]}

Simon, N.

Ballutaud, D.

de La Rochefoucauld, E.

Etcheberry, A.

机构：

[1] Univ Versailles, Inst Lavoisier Versailles, St Quentin en Yvelines, France

[2] CNRS, Grp Etud Mat Condensee, Meudon, France

来源：

关键词：

diamond; anodic treatment; hydrogenated diamond; charge transfer; superficial conductive layer; wettability;

D O I：

10.1016/j.diamond.2006.12.002

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrochemical behaviour of as-deposited and anodically treated samples is studied by cyclic voltammetry in the presence of redox couple (Ce4+/Ce3+). Two kinds of anodic pre-treatments are performed, playing on the current density and on the duration of the galvanostatic step. Mott-Schottky plots are reported, and related to the energy band diagram evolution of the electrodes after anodic processes. The electrochemical behaviour modification is correlated to the surface wettability evolution and flat band potential shift. For mild anodic pre-treatments, a conservation of the superficial conductive layer (SCL), known to exist on hydrogen-terminated boron doped diamond (BDD), is proposed, while for strong treatments, the SCL disappears. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：888 / 891

页数：4

共 14 条

[1] Influence of surface modifications on the electronic properties of CVD diamond films [J].

Bachmann, PK ;

Eberhardt, W ;

Kessler, B ;

Lade, H ;

Radermacher, K ;

Wiecher, DU ;

Wilson, H .

[2] Boron doped diamond/titanium composite electrodes for electrochemical gas generation from aqueous electrolytes [J].

Beck, F ;

Krohn, H ;

Kaiser, W ;

Fryda, M ;

Klages, CP ;

Schafer, L .

ELECTROCHIMICA ACTA, 1998, 44 (2-3) :525-532

[3] Electrochemistry of the aqueous europium(III)/europium(II) redox couple at conductive diamond electrodes [J].

Ferro, S ;

De Battisti, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2002, 533 (1-2) :177-180

[4] Effect of anodic and cathodic treatments on the charge transfer of boron doped diamond electrodes [J].

Girard, H. ;

Simon, N. ;

Ballutaud, D. ;

Herlern, M. ;

Etcheberry, A. .

[5] The influence of surface interactions on the reversibility of ferri/ferrocyanide at boron-doped diamond thin-film electrodes [J].

Granger, MC ;

Swain, GM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (12) :4551-4558

[6] Investigation of the effect of hydrogen on electrical and optical properties in chemical vapor deposited on homoepitaxial diamond films [J].

Hayashi, K ;

Yamanaka, S ;

Watanabe, H ;

Sekiguchi, T ;

Okushi, H ;

Kajimura, K .

JOURNAL OF APPLIED PHYSICS, 1997, 81 (02) :744-753

[7] The electrochemical response of highly boron-doped conductive diamond electrodes to Ce3+ ions in aqueous solution [J].

Maeda, Y ;

Sato, K ;

Ramaraj, R ;

Rao, TN ;

Tryk, DA ;

Fujishima, A .

ELECTROCHIMICA ACTA, 1999, 44 (20) :3441-3449

[8] Origin of surface conductivity in diamond [J].

Maier, F ;

Riedel, M ;

Mantel, B ;

Ristein, J ;

Ley, L .

PHYSICAL REVIEW LETTERS, 2000, 85 (16) :3472-3475

[9] Electrochemical studies of moderately boron doped polycrystalline diamond in non-aqueous solvent [J].

Pastor-Moreno, G ;

Riley, DJ .

ELECTROCHIMICA ACTA, 2002, 47 (16) :2589-2595

[10] Electrochemical characterization of intrinsic hydrogen terminated single crystalline CVD diamond [J].

Shin, D ;

Watanabe, H ;

Nebel, CE .

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2005, 202 (11) :2104-2109

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