Gated Molecular Diffusion at Liquid-Liquid Interfaces

被引：28
作者：
Li, Lianshun [1 ]
Sun, Huilou [1 ]
Li, Mingwei [1 ]
Yang, Yang [1 ]
Russell, Thomas P. [2 ,3 ]
Shi, Shaowei [1 ]
机构：
[1] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China
[2] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
[3] Lawrence Berkeley Natl Lab, Div Mat Sci, 1 Cyclotron Rd, Berkeley, CA 94720 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2021年 / 60卷 / 32期
基金：
中国国家自然科学基金; 北京市自然科学基金;
关键词：
host-guest chemistry; interface; jamming; microcapsules; nanoparticle surfactants; CROSS-LINKING; STRUCTURED LIQUIDS; NANOPARTICLES; COLLOIDOSOMES; WETTABILITY; CAPSULES;
D O I：
10.1002/anie.202105500
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The jamming of nanoparticle surfactants (NPSs) at liquid-liquid interface imparts attractive properties to the interfacial assemblies and enables the structuring of liquids. Herein, we report photoresponsive supramolecular microcapsules with jammed NPS assemblies at the oil-water interface, taking advantage of host-guest molecular recognition. The permeability of the colloidal membrane can be effectively manipulated by switching the NPSs from a jammed state to an unjammed state with a photo trigger, leading to a controlled molecular diffusion and release, affording a versatile platform for the construction of next generation smart microcapsule systems.
引用
收藏
页码：17394 / 17397
页数：4
相关论文
共 50 条
  • [31] Influence of mixing intensity on the mass transfer coefficient across liquid-liquid interfaces
    Al-Dahhan, MH
    Wicks, CE
    CHEMICAL ENGINEERING COMMUNICATIONS, 1996, 145 : 213 - 227
  • [32] Heterogeneous or competitive self-assembly of surfactants and nanoparticles at liquid-liquid interfaces
    Luo, Mingxiang
    Song, Yanmei
    Dai, Lenore L.
    MOLECULAR SIMULATION, 2009, 35 (10-11) : 773 - 784
  • [33] Mapping and Tuning the Fluorescence of Perfluorinated Polyanilines Synthesized through Liquid-Liquid Interfaces
    Dallas, Panagiotis
    Rasovic, Ilija
    Porfyrakis, Kyriakos
    JOURNAL OF PHYSICAL CHEMISTRY B, 2016, 120 (13) : 3441 - 3454
  • [34] Particle Lithography from Colloidal Self-Assembly at Liquid-Liquid Interfaces
    Isa, Lucio
    Kumar, Karthik
    Mueller, Mischa
    Grolig, Jan
    Textor, Marcus
    Reimhult, Erik
    ACS NANO, 2010, 4 (10) : 5665 - 5670
  • [35] Nanoparticles migration near liquid-liquid interfaces using diffuse interface model
    Daher, Ali
    Ammar, Amine
    Hijazi, Abbas
    ENGINEERING COMPUTATIONS, 2019, 36 (03) : 1036 - 1054
  • [36] Hydrogen Evolution Catalyzed by Cu2WS4 at Liquid-Liquid Interfaces
    Ozel, Faruk
    Aslan, Emre
    Sarilmaz, Adem
    Patir, Imren Hatay
    ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (39) : 25881 - 25887
  • [37] Non-linear dilational rheology of liquid-liquid interfaces stabilized by dipeptide hydrogels
    Carbonell-Avino, Fernando
    Clegg, Paul S.
    RHEOLOGICA ACTA, 2023, 62 (01) : 45 - 55
  • [38] Non-linear dilational rheology of liquid-liquid interfaces stabilized by dipeptide hydrogels
    Fernando Carbonell-Aviñó
    Paul S. Clegg
    Rheologica Acta, 2023, 62 : 45 - 55
  • [39] Liquid-Liquid Phase Separation at Double Emulsion Interfaces: Equilibrium Structures and Dynamic Pathways
    Zhao, Yue
    Li, Baihui
    Chen, Xiaotong
    Zhou, Yue
    Song, Tiantian
    Shi, Weichao
    MACROMOLECULES, 2023, 56 (21) : 8834 - 8844
  • [40] Contact Angle, Liquid Film, and Liquid-Liquid and Liquid-Solid Interfaces in Model Oil-Brine-Substrate Systems
    Jimenez-Angeles, Felipe
    Firoozabadi, Abbas
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (22) : 11910 - 11917
12345