Gated Molecular Diffusion at Liquid-Liquid Interfaces

被引：28
作者：
Li, Lianshun [1 ]
Sun, Huilou [1 ]
Li, Mingwei [1 ]
Yang, Yang [1 ]
Russell, Thomas P. [2 ,3 ]
Shi, Shaowei [1 ]
机构：
[1] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China
[2] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
[3] Lawrence Berkeley Natl Lab, Div Mat Sci, 1 Cyclotron Rd, Berkeley, CA 94720 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2021年 / 60卷 / 32期
基金：
中国国家自然科学基金; 北京市自然科学基金;
关键词：
host-guest chemistry; interface; jamming; microcapsules; nanoparticle surfactants; CROSS-LINKING; STRUCTURED LIQUIDS; NANOPARTICLES; COLLOIDOSOMES; WETTABILITY; CAPSULES;
D O I：
10.1002/anie.202105500
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The jamming of nanoparticle surfactants (NPSs) at liquid-liquid interface imparts attractive properties to the interfacial assemblies and enables the structuring of liquids. Herein, we report photoresponsive supramolecular microcapsules with jammed NPS assemblies at the oil-water interface, taking advantage of host-guest molecular recognition. The permeability of the colloidal membrane can be effectively manipulated by switching the NPSs from a jammed state to an unjammed state with a photo trigger, leading to a controlled molecular diffusion and release, affording a versatile platform for the construction of next generation smart microcapsule systems.
引用
收藏
页码：17394 / 17397
页数：4
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