Gated Molecular Diffusion at Liquid-Liquid Interfaces

被引：28
作者：
Li, Lianshun [1 ]
Sun, Huilou [1 ]
Li, Mingwei [1 ]
Yang, Yang [1 ]
Russell, Thomas P. [2 ,3 ]
Shi, Shaowei [1 ]
机构：
[1] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China
[2] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
[3] Lawrence Berkeley Natl Lab, Div Mat Sci, 1 Cyclotron Rd, Berkeley, CA 94720 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2021年 / 60卷 / 32期
基金：
中国国家自然科学基金; 北京市自然科学基金;
关键词：
host-guest chemistry; interface; jamming; microcapsules; nanoparticle surfactants; CROSS-LINKING; STRUCTURED LIQUIDS; NANOPARTICLES; COLLOIDOSOMES; WETTABILITY; CAPSULES;
D O I：
10.1002/anie.202105500
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The jamming of nanoparticle surfactants (NPSs) at liquid-liquid interface imparts attractive properties to the interfacial assemblies and enables the structuring of liquids. Herein, we report photoresponsive supramolecular microcapsules with jammed NPS assemblies at the oil-water interface, taking advantage of host-guest molecular recognition. The permeability of the colloidal membrane can be effectively manipulated by switching the NPSs from a jammed state to an unjammed state with a photo trigger, leading to a controlled molecular diffusion and release, affording a versatile platform for the construction of next generation smart microcapsule systems.
引用
收藏
页码：17394 / 17397
页数：4
相关论文
共 50 条
  • [1] Host-Guest Molecular Recognition at Liquid-Liquid Interfaces
    Wang, Beibei
    Chen, Hao
    Liu, Tan
    Shi, Shaowei
    Russell, Thomas P.
    ENGINEERING, 2021, 7 (05) : 603 - 614
  • [2] Janus Cylinders at Liquid-Liquid Interfaces
    Ruhland, Thomas M.
    Groeschel, Andre H.
    Wather, Andreas
    Mueller, Axel H. E.
    LANGMUIR, 2011, 27 (16) : 9807 - 9814
  • [3] Photoresponsive Structured Liquids Enabled by Molecular Recognition at Liquid-Liquid Interfaces
    Sun, Huilou
    Li, Lianshun
    Russell, Thomas P.
    Shi, Shaowei
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (19) : 8591 - 8595
  • [4] Nanoparticle Assembly at Liquid-Liquid Interfaces: From the Nanoscale to Mesoscale
    Shi, Shaowei
    Russell, Thomas P.
    ADVANCED MATERIALS, 2018, 30 (44)
  • [5] The Assembly and Jamming of Nanoparticle Surfactants at Liquid-Liquid Interfaces
    Wang, Beibei
    Yin, Bangqi
    Zhang, Zhao
    Yin, Yixuan
    Yang, Yang
    Wang, Haiqiao
    Russell, Thomas P.
    Shi, Shaowei
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (10)
  • [6] Elastic capsules at liquid-liquid interfaces
    Hegemann, Jonas
    Boltz, Horst-Holger
    Kierfeld, Jan
    SOFT MATTER, 2018, 14 (27) : 5665 - 5685
  • [7] Control of Surface Tension at Liquid-Liquid Interfaces Using Nanoparticles and Nanoparticle-Protein Complexes
    Rana, Subinoy
    Yu, Xi
    Patra, Debabrata
    Moyano, Daniel F.
    Miranda, Oscar R.
    Hussain, Irshad
    Rotello, Vincent M.
    LANGMUIR, 2012, 28 (04) : 2023 - 2027
  • [8] Soft Polymer Janus Nanoparticles at Liquid-Liquid Interfaces
    Jiang, Yufeng
    Chakroun, Ramzi
    Gu, Peiyang
    Groeschel, Andre H.
    Russell, Thomas P.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (31) : 12751 - 12755
  • [9] Janus Dimers at Liquid-Liquid Interfaces
    Borowko, M.
    Slyk, E.
    Sokolowski, S.
    Staszewski, T.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2019, 123 (18) : 4139 - 4147
  • [10] Adsorption of core-shell nanoparticles at liquid-liquid interfaces
    Isa, Lucio
    Amstad, Esther
    Schwenke, Konrad
    Del Gado, Emanuela
    Ilg, Patrick
    Kroeger, Martin
    Reimhult, Erik
    SOFT MATTER, 2011, 7 (17) : 7663 - 7675
12345