catena-Poly[[copper(II)-bis(μ-3-carboxypyridine-2-carboxylato)-κ3N,O2;O3;κ3O3:N,O2]methanol disolvate]

被引：9

作者：

Turner, David R. ^{[1
]}

Batten, Stuart R. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807000499

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, {[Cu(C7H4O4)(2)]center dot 2CH(3)OH}(n), forms a square-planar complex through two N,O-chelating pyridine-2,3-dicarboxylate ligands. Axial interactions between Cu-II and O atoms of the CO2H groups in the meta-positions of adjacent ligands form one-dimensional chains. Incorporation of methanol into the structure results in O-H center dot center dot center dot O hydrogen-bond interactions, which cross-link the chains into a three-dimensional network.

引用

页码：M452 / M454

页数：3

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