The entropies of solvation and transfer of ions in the water-ethanol binary system at 298.15 K

被引：0
|
作者：
Sokolov, VN [1 ]
Kobenin, VA [1 ]
Gorelov, VN [1 ]
机构：
[1] Ivanovo State Univ Chem Technol, Ivanovo 153460, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2005年 / 79卷 / 02期
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D O I：
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The entropies of solvation and transfer of ions in aqueous ethanol were determined from the data obtained by measuring the initial and stationary temperature coefficients of the voltage of thermogalvanic circuits with silver-chloride and quinhydrone electrodes in the system HCl-H2O-C2H5OH. The influence of the composition of the mixed solvent and the nature of the ions on the entropy characteristics was analyzed.
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页码：168 / 172
页数：5
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