CoNi2S4-Graphene-2D-MoSe2 as an Advanced Electrode Material for Supercapacitors

被引:169
作者
Shen, Jianfeng [1 ,2 ]
Wu, Jingjie [2 ]
Pei, Liyuan [1 ]
Rodrigues, Marco-Tulio F. [2 ]
Zhang, ZhuQing [1 ]
Zhang, Fangfang [1 ]
Zhang, Xiang [2 ]
Ajayan, Pulickel M. [2 ]
Ye, Mingxin [1 ]
机构
[1] Fudan Univ, Inst Special Mat & Technol, Shanghai 200433, Peoples R China
[2] Rice Univ, Dept Mat Sci & NanoEngn, 6100 Main St, Houston, TX 77005 USA
基金
中国国家自然科学基金;
关键词
TRANSITION-METAL DICHALCOGENIDES; STATE ASYMMETRIC SUPERCAPACITORS; NICO2S4 NANOTUBE ARRAYS; HIGH-ENERGY DENSITY; CARBON-FIBER PAPER; IN-SITU GROWTH; MICRO-SUPERCAPACITORS; NANOWIRE ARRAYS; CHARGE-TRANSFER; NI FOAM;
D O I
10.1002/aenm.201600341
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
3D CoNi2S4-graphene-2D-MoSe2 (CoNi2S4-G-MoSe2) nanocomposite is designed and prepared using a facile ultrasonication and hydrothermal method for supercapacitor (SC) applications. Because of the novel nanocomposite structures and resultant maximized synergistic effect among ultrathin MoSe2 nanosheets, highly conductive graphene and CoNi2S4 nanoparticles, the electrode exhibits rapid electron and ion transport rate and large electroactive surface area, resulting in its amazing electrochemical properties. The CoNi2S4-G-MoSe2 electrode demonstrates a maximum specific capacitance of 1141 F g(-1), with capacitance retention of approximate to 108% after 2000 cycles at a high charge-discharge current density of 20 A g(-1). As to its symmetric device, 109 F g(-1) at a scan rate of 5 mV s(-1) is exhibited. This pioneering work should be helpful in enhancing the capacitive performance of SC materials by designing nanostructures with efficient synergetic effects.
引用
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页数:8
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