A New Crosslinked Sulfonated Polystyrene for Proton Exchange Fuel Cell Membrane

被引：10

作者：

Xu, Jing ^{[1
]}

Yu, Jianjia ^{[1
]}

Guan, Rong ^{[1
]}

Li, Cuihua ^{[2
]}

Sun, Lingna ^{[2
]}

Fang, Jianhua ^{[3
]}

机构：

[1] Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China

[2] Shenzhen Univ, Coll Chem & Chem Engn, Shenzhen 518060, Peoples R China

[3] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China

来源：

HIGH PERFORMANCE POLYMERS | 2010年 / 22卷 / 04期

关键词：

Polystyrene; crosslinking; membrane; swelling ratio; conductivity; POLY(ARYLENE ETHER SULFONE); WATER STABILITY; CONDUCTIVITY; POLYIMIDES; POLYELECTROLYTES; COPOLYMERS;

D O I：

10.1177/0954008309105515

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of crosslinked sulfonated polystyrene (SPS) membranes with different degree of sulfonation (DS) were prepared in the presence of phosphorous pentoxide-methanesulfonic acid (PPMA) in the ratio of 1:10 by weight via the condensation reaction between the sulfonic acid groups and the activated hydrogen atoms of SPS. The crosslinking reaction was confirmed by H-1-NMR and Fourier transform infrared spectrometry. In comparison with uncrosslinked SPS membrane, the crosslinked one showed much higher thermal stability as the degradation temperature increased from about 200 to 300 degrees C, lower but enough ion exchange capacity (IEC), lower water uptake, and lower swelling ratio. Moreover, the crosslinked SPS membranes still maintained high proton conductivity (3.3-6.1 x 10(-2) S cm(-1)) and keep good shape at room temperature in 100% relative humidity. The relationships among crosslinking time, crosslinking ratio, DS and membrane properties are discussed.

引用

页码：395 / 411

页数：17

共 28 条

[1] Ionomeric membranes based on partially sulfonated poly(styrene): synthesis, proton conduction and methanol permeation
Carretta, N
Tricoli, V
Picchioni, F
[J]. JOURNAL OF MEMBRANE SCIENCE, 2000, 166 (02) : 189 - 197
[2] FANG J, 2005, Patent No. 1730517
[3] Novel sulfonated polyimides as polyelectrolytes for fuel cell application.: 1.: Synthesis, proton conductivity, and water stability of polyimides from 4,4′-diaminodiphenyl ether-2,2′-disulfonic acid
Fang, JH
Guo, XX
Harada, S
Watari, T
Tanaka, K
Kita, H
Okamoto, K
[J]. MACROMOLECULES, 2002, 35 (24) : 9022 - 9028
[4] A facile approach for the preparation of cross-linked sulfonated polyimide membranes for fuel cell application
Fang, Jianhua
Zhai, Fengxia
Guo, Xiaoxia
Xu, Hongjie
Okamoto, Ken-ichi
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (11) : 1102 - 1108
[5] New multiblock copolymers of sulfonated poly(4′-phenyl-2,5-benzophenone) and poly(arylene ether sulfone) for proton exchange membranes.: II
Ghassemi, H
Ndip, G
McGrath, JE
[J]. POLYMER, 2004, 45 (17) : 5855 - 5862
[6] Synthesis and properties of new sulfonated poly(p-phenylene) derivatives for proton exchange membranes.: I
Ghassemi, H
McGrath, JE
[J]. POLYMER, 2004, 45 (17) : 5847 - 5854
[7] Novel sulfonated polyimides as polyelectrolytes for fuel cell application. 2. Synthesis and proton conductivity, of polyimides from 9,9-bis(4-aminophenyl)fluorene-2,7-disulfonic acid
Guo, XX
Fang, JH
Watari, T
Tanaka, K
Kita, H
Okamoto, KI
[J]. MACROMOLECULES, 2002, 35 (17) : 6707 - 6713
[8] Alternative polymer systems for proton exchange membranes (PEMs)
Hickner, MA
Ghassemi, H
Kim, YS
Einsla, BR
McGrath, JE
[J]. CHEMICAL REVIEWS, 2004, 104 (10) : 4587 - 4611
[9] Development of ionomer membranes for fuel cells
Kerres, JA
[J]. JOURNAL OF MEMBRANE SCIENCE, 2001, 185 (01) : 3 - 27
[10] Proton-conducting polymers derived from poly(ether-etherketone) and poly(4-phenoxybenzoyl-1,4-phenylene)
Kobayashi, T
Rikukawa, M
Sanui, K
Ogata, N
[J]. SOLID STATE IONICS, 1998, 106 (3-4) : 219 - 225

← 1 2 3 →