Oxidation of alkyl benzenes by a flavin photooxidation catalyst on nanostructured metal-oxide films

被引：31
作者：
Dongare, Prateek [1 ]
MacKenzie, Ian [1 ]
Wang, Degao [1 ]
Nicewicz, David A. [1 ]
Meyer, Thomas J. [1 ]
机构：
[1] Univ North Carolina Chapel Hill, Dept Chem, Chapel Hill, NC 27599 USA
来源：
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2017年 / 114卷 / 35期
基金：
美国国家科学基金会;
关键词：
flavin; excited state; photooxidation; oxide surface; alkyl benzene; ELECTRON-TRANSFER; REDUCTION; WATER; SUBSTITUTION; CHEMISTRY; OXYGEN; MODEL;
D O I：
10.1073/pnas.1707318114
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
We describe here a surface-bound, oxide-based procedure for the photooxidation of a family of aromatic hydrocarbons by a phosphate-bearing flavin mononucleotide (FMN) photocatalyst on high surface area metal-oxide films.
引用
收藏
页码：9279 / 9283
页数：5
相关论文
共 42 条
  • [1] Molecular Chromophore-Catalyst Assemblies for Solar Fuel Applications
    Ashford, Dennis L.
    Gish, Melissa K.
    Vannucci, Aaron K.
    Brennaman, M. Kyle
    Templeton, Joseph L.
    Papanikolas, John M.
    Meyer, Thomas J.
    [J]. CHEMICAL REVIEWS, 2015, 115 (23) : 13006 - 13049
  • [2] MECHANISMS OF FLAVIN CATALYSIS
    BRUICE, TC
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1980, 13 (08) : 256 - 262
  • [3] Model systems for flavoenzyme activity: Site-isolated redox behavior in flavin-functionalized random polystyrene copolymers
    Carroll, JB
    Jordan, BJ
    Xu, H
    Erdogan, B
    Lee, L
    Cheng, L
    Tiernan, C
    Cooke, G
    Rotello, VM
    [J]. ORGANIC LETTERS, 2005, 7 (13) : 2551 - 2554
  • [4] Specific Photobiocatalytic Oxyfunctionalization Reactions
    Churakova, Ekaterina
    Kluge, Martin
    Ullrich, Rene
    Arends, Isabel
    Hofrichter, Martin
    Hollmann, Frank
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (45) : 10716 - 10719
  • [5] Photooxidation of Sulfides to Sulfoxides Mediated by Tetra-O-Acetylriboflavin and Visible Light
    Dad'ova, Jitka
    Svobodova, Eva
    Sikorski, Marek
    Koenig, Burkhard
    Cibulka, Radek
    [J]. CHEMCATCHEM, 2012, 4 (05) : 620 - 623
  • [6] ONE-ELECTRON AND 2-ELECTRON REDUCTION OF OXYGEN BY 1,5-DIHYDROFLAVINS
    EBERLEIN, G
    BRUICE, TC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (05) : 1449 - 1452
  • [7] Edwards A.M., 2006, CHAPTER 1 GEN PROPER, V6, P1, DOI DOI 10.1039/9781847555397-00001
  • [8] FLAVIN-SENSITIZED PHOTO-OXIDATION OF UNSATURATED FATTY-ACIDS
    FUKUZUMI, S
    TANII, K
    TANAKA, T
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (12): : 2103 - 2108
  • [9] Synthetic Applications of Proton-Coupled Electron Transfer
    Gentry, Emily C.
    Knowles, Robert R.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (08) : 1546 - 1556
  • [10] Stabilizing Small Molecules on Metal Oxide Surfaces Using Atomic Layer Deposition
    Hanson, Kenneth
    Losego, Mark D.
    Kalanyan, Berc
    Parsons, Gregory N.
    Meyer, Thomas J.
    [J]. NANO LETTERS, 2013, 13 (10) : 4802 - 4809
12345