Selective Catalytic Reductions of Amides and Nitriles to Amines

被引:101
作者
Das, Shoubhik [1 ]
Zhou, Shaolin [1 ]
Addis, Daniele [1 ]
Enthaler, Stephan [1 ]
Junge, Kathrin [1 ]
Beller, Matthias [1 ]
机构
[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany
关键词
Catalysis; Reduction; Hydrogenation; Hydrosilylation; Amides; Nitriles; Amines; ANTI-MARKOVNIKOV HYDROAMINATION; TERTIARY-AMINES; CHEMOSELECTIVE HYDROGENATION; DIHYDROGEN REDUCTION; RUTHENIUM COMPLEXES; SELF-ENCAPSULATION; SILANE REDUCTION; METAL-CATALYSTS; IRON; HYDROSILYLATION;
D O I
10.1007/s11244-010-9526-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This personal account summarizes our recent developments of catalytic hydrosilylations and hydrogenations of carboxylic amides and nitriles to selectively give amines. Special focus is given to highly chemoselective iron- and zinc-catalyzed reductions of amides.
引用
收藏
页码:979 / 984
页数:6
相关论文
共 96 条
[1]   Chemo- and Stereoselective Iron-Catalyzed Hydrosilylation of Ketones [J].
Addis, Daniele ;
Shaikh, Nadim ;
Zhou, Shaolin ;
Das, Shoubhik ;
Junge, Kathrin ;
Beller, Matthius .
CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) :1687-1691
[2]   Ruthenium N-heterocyclic carbene catalysts for selective reduction of nitriles to primary amines [J].
Addis, Daniele ;
Enthaler, Stephan ;
Junge, Kathrin ;
Wendt, Bianca ;
Beller, Matthias .
TETRAHEDRON LETTERS, 2009, 50 (26) :3654-3656
[3]   Amines made easily: A highly selective hydroaminomethylation of olefins [J].
Ahmed, M ;
Seayad, AM ;
Jackstell, R ;
Beller, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10311-10318
[4]   Hydroaminomethylation with novel rhodium-carbene complexes: An efficient catalytic approach to pharmaceuticals [J].
Ahmed, Moballigh ;
Buch, Cathleen ;
Routaboul, Lucie ;
Jackstell, Ralf ;
Klein, Holger ;
Spannenberg, Anke ;
Beller, Matthias .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (05) :1594-1601
[5]   Highly selective hydroaminomethylation of internal alkenes to give linear amines [J].
Ahmed, Moballigh ;
Bronger, Raymond P. J. ;
Jackstell, Ralf ;
Kamer, Paul C. L. ;
van Leeuwen, Piet W. N. M. ;
Beller, Matthias .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (35) :8979-8988
[6]   General zinc-catalyzed intermolecular hydroamination of terminal alkynes [J].
Alex, Karolin ;
Tillack, Annegret ;
Schwarz, Nicolle ;
Beller, Matthias .
CHEMSUSCHEM, 2008, 1 (04) :333-338
[7]   Zinc-promoted hydrohydrazination of terminal alkynes: An efficient domino synthesis of indoles [J].
Alex, Karolin ;
Tillack, Annegret ;
Schwarz, Nicolle ;
Beller, Matthias .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (12) :2304-2307
[8]  
Anderson P. G, 2008, MODERN REDUCTION MET
[9]   Concomitant monoreduction and hydrogenation of unsaturated cyclic imides to lactams catalyzed by ruthenium compounds [J].
Aoun, R ;
Renaud, JL ;
Dixneuf, PH ;
Bruneau, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (13) :2021-2023
[10]   Ruthenium-catalyzed synthesis of secondary alkylamines:: Selective alkylation with aliphatic amines [J].
Baehn, Sebastian ;
Hollmann, Dirk ;
Tillack, Annegret ;
Beller, Matthias .
ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (13) :2099-2103