The effect of microstructure and secondary phase on magnetic and electrical properties of La-deficient La1-xMnO3-δ (0 ≤ x ≤ 0.3) films

被引:25
作者
Chen, GJ [1 ]
Chang, YH [1 ]
Hsu, HW [1 ]
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan
关键词
microstructure; lanthanum deficiency; magnetoresistance; magnetization; resistivity;
D O I
10.1016/S0304-8853(00)00463-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effects of La-deficiency on the microstructure, magnetic and electrical properties of lanthanum manganite films are reported. By high-resolution transmission electron microscopy observations, the irradiation damages were found due to the introduction of vacancies. With proper control of La ions, the magnetic transition temperature was elevated to higher than room temperature. An insulator-metal transition (I-M transition) was observed for all La1-xMnO3-delta films. The large negative magnetoresistance effect is demonstrated. In addition, the influence of the secondary-phase Mn3O4 on the properties of the films is studied. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:317 / 324
页数:8
相关论文
共 21 条
[1]   Magnetic structures of LaMnO3+delta perovskites (delta=0.11, 0.15, 0.26) [J].
Alonso, JA ;
MartinezLope, MJ ;
Casais, MT ;
Munoz, A .
SOLID STATE COMMUNICATIONS, 1997, 102 (01) :7-12
[2]   Insulator-metal transitions, giant magnetoresistance, and related aspects of the cation-deficient LaMnO3 compositions La1-delta MnO3 and LaMn1-delta O3 [J].
Arulraj, A ;
Mahesh, R ;
Subbanna, GN ;
Mahendiran, R ;
Raychaudhuri, AK ;
Rao, CNR .
JOURNAL OF SOLID STATE CHEMISTRY, 1996, 127 (01) :87-91
[3]   A STRUCTURAL PHASE-TRANSITION INDUCED BY AN EXTERNAL MAGNETIC-FIELD [J].
ASAMITSU, A ;
MORITOMO, Y ;
TOMIOKA, Y ;
ARIMA, T ;
TOKURA, Y .
NATURE, 1995, 373 (6513) :407-409
[4]   ORDERED LA(SR)-DEFICIENT NONSTOICHIOMETRY IN LA0.8SR0.2MNO3 OBSERVED BY HIGH-RESOLUTION TRANSMISSION ELECTRON-MICROSCOPY [J].
CERVA, H .
JOURNAL OF SOLID STATE CHEMISTRY, 1995, 120 (01) :175-181
[5]   Magnetic and electrical properties of perovskite La1-xMnO3-δ films [J].
Chen, GJ ;
Chang, YH ;
Hsu, HW .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1999, 68 (02) :104-110
[6]   EFFECTS OF DOUBLE EXCHANGE IN MAGNETIC CRYSTALS [J].
DEGENNES, PG .
PHYSICAL REVIEW, 1960, 118 (01) :141-154
[7]   REACTIONS AT THE INTERFACES OF THIN-FILMS OF Y-BA-CU-OXIDES AND ZR-OXIDES WITH SI SUBSTRATES [J].
FENNER, DB ;
VIANO, AM ;
FORK, DK ;
CONNELL, GAN ;
BOYCE, JB ;
PONCE, FA ;
TRAMONTANA, JC .
JOURNAL OF APPLIED PHYSICS, 1991, 69 (04) :2176-2182
[8]   Effect of nonstoichiometry on properties of La1-tMnO3+delta .3. Magnetic order studied by powder neutron diffraction [J].
Hauback, BC ;
Fjellvag, H ;
Sakai, N .
JOURNAL OF SOLID STATE CHEMISTRY, 1996, 124 (01) :43-51
[9]   Spin-polarized intergrain tunneling in La-2/Sr-3(1)/3MnO3 [J].
Hwang, HY ;
Cheong, SW ;
Ong, NP ;
Batlogg, B .
PHYSICAL REVIEW LETTERS, 1996, 77 (10) :2041-2044
[10]   THOUSANDFOLD CHANGE IN RESISTIVITY IN MAGNETORESISTIVE LA-CA-MN-O FILMS [J].
JIN, S ;
TIEFEL, TH ;
MCCORMACK, M ;
FASTNACHT, RA ;
RAMESH, R ;
CHEN, LH .
SCIENCE, 1994, 264 (5157) :413-415