p-cumylphenyl methacrylate: Synthesis, polymerization, and copolymerization

被引：4

作者：

Bindushree, CV ^{[1
]}

Venkataramanan, B ^{[1
]}

Khisti, RS ^{[1
]}

Sivaram, S ^{[1
]}

机构：

[1] Natl Chem Lab, Div Polymer Chem, Pune 411008, Maharashtra, India

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1998年 / A35卷 / 01期

关键词：

D O I：

10.1080/10601329808001970

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new methacrylic monomer from the reaction of methacryloyl chloride with p-cumylphenol has been synthesized. The effect of sterically bulky p-cumylphenyl group on homopolymerization and copolymerization was examined. In copolymers, p-cumylphenyl methacrylate increases the T-g of acrylic polymers. The T-g of the copolymers as determined by DSC agrees with both the Flory-Fox and Gordon-Taylor relationships.

引用

页码：183 / 191

页数：9

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