Nanoscale Aggregation in Acid- and Ion-Containing Polymers

被引:48
|
作者
Middleton, L. Robert [1 ]
Winey, Karen I. [1 ]
机构
[1] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
来源
ANNUAL REVIEW OF CHEMICAL AND BIOMOLECULAR ENGINEERING, VOL 8 | 2017年 / 8卷
基金
美国国家科学基金会;
关键词
ionomers; solid polymer electrolytes; associating polymers; SULFONATED POLYSTYRENE IONOMERS; X-RAY-SCATTERING; MOLECULAR-DYNAMICS SIMULATIONS; SHAPE-MEMORY BEHAVIOR; PRECISE ACID; CONTAINING POLYETHYLENES; MAS NMR; LINEAR VISCOELASTICITY; ELECTRON-MICROSCOPY; REVERSIBLE GELATION;
D O I
10.1146/annurev-chembioeng-060816-101531
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this review we summarize recent efforts in understanding nano-aggregation in acid-and ion-containing polymer systems. The acid and ionic groups have specific interactions that drive aggregation and alter polymer behavior at the nano-, micro-, and bulk length scales. Advancements in synthetic methods, characterization techniques, and computer simulations have enabled researchers to better understand the morphologies and dynamics, particularly at the nanoscale. This overview of recent advancements in nano-aggregated polymer systems highlights the current understanding of the field and presents promising directions for future investigations and new applications.
引用
收藏
页码:499 / 523
页数:25
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