Room temperature synthesis of stable single silica-coated CsPbBr3 quantum dots combining tunable red emission of Ag-In-Zn-S for High-CRI white light-emitting diodes

被引:237
作者
Guan, Hongling [1 ]
Zhao, Shuangyi [1 ]
Wang, Huaxin [1 ]
Yan, Dongdong [1 ]
Wang, Ming [1 ]
Zang, Zhigang [1 ]
机构
[1] Chongqing Univ, Key Lab Optoelect Technol & Syst, Minist Educ, Chongqing 400044, Peoples R China
基金
中国国家自然科学基金;
关键词
CsPbBr3; QDs; Stability; Ag-In-Zn-S QDs; WLEDs; INORGANIC PEROVSKITE NANOCRYSTALS; LEAD HALIDE PEROVSKITES; LARGE-SCALE SYNTHESIS; NANOWIRE LASERS; HIGH-QUALITY; EFFICIENT; PHOSPHORS; PHOTOLUMINESCENCE; CSPBX3; CL;
D O I
10.1016/j.nanoen.2019.104279
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
White light emitting diodes (WLEDs) based on all-inorganic halide (CsPbX3, X = Cl, Br and I) perovskite quantum dots (QDs) have attracted broad attention due to their high brightness. However, their poor stability and anionexchange reaction when utilized together are still the main challenges that impede their applications. Herein, a one-step in situ method under room temperature in air is proposed to synthesize CsPbBr3 QDs coated with SiO2 (CsPbBr3@SiO2), where the whole process takes only 20 s. The as-prepared CsPbBr3@SiO2 QDs samples present an enhanced stability in the thermal and polar-solvent environment, maintaining its high photoluminescence quantum yield (PLQY-75%). Thereby WLEDs are constructed by combining CsPbBr3@SiO2 with red Ag-In-Zn-S QDs on InGaN blue chip, achieving a high color rendering index (CRI) of 91, a correlated color temperature (CCT) of 3689 K and a power efficiency of 40.6 lm(-)(1).
引用
收藏
页数:9
相关论文
共 21 条
  • [1] Highly efficient emission and high-CRI warm white light-emitting diodes from ligand-modified CsPbBr3 quantum dots
    Yan, Dongdong
    Zhao, Shuangyi
    Zhang, Yubo
    Wang, Huaxin
    Zang, Zhigang
    OPTO-ELECTRONIC ADVANCES, 2022, 5 (01)
  • [2] Sol-Gel Synthesis of Thermally Stable and Waterproof Silica-Coated CsPbBr3 Nanocrystals for White Light-Emitting Diodes
    Chen, Yanhui
    Zhang, Rui
    Xu, Zusheng
    Qin, Xianzhuang
    ACS APPLIED NANO MATERIALS, 2023, 6 (24) : 23122 - 23129
  • [3] Room temperature synthesis of Sn2+ doped highly luminescent CsPbBr3 quantum dots for high CRI white light-emitting diodes
    Yan, Dongdong
    Mo, Qionghua
    Zhao, Shuangyi
    Cai, Wensi
    Zang, Zhigang
    NANOSCALE, 2021, 13 (21) : 9740 - 9746
  • [4] Room Temperature Synthesis of Stable Zirconia-Coated CsPbBr3 Nanocrystals for White Light-Emitting Diodes and Visible Light Communication
    Mo, Qionghua
    Chen, Chen
    Cai, Wensi
    Zhao, Shuangyi
    Yan, Dongdong
    Zang, Zhigang
    LASER & PHOTONICS REVIEWS, 2021, 15 (10)
  • [5] Highly stable CsPbBr3 quantum dots by silica-coating and ligand modification for white light-emitting diodes and visible light communication
    Li, Xianwen
    Cai, Wensi
    Guan, Hongling
    Zhao, Shuangyi
    Cao, Siliang
    Chen, Chen
    Liu, Min
    Zang, Zhigang
    CHEMICAL ENGINEERING JOURNAL, 2021, 419
  • [6] Low-Temperature Synthesis of High-Brightness Green-Emitting Silica-Coated CsPbBr3 and Its Application in Light-Emitting Diodes
    Zhang, Lu
    Gao, Yunlong
    Cao, Peiyuan
    Yang, Bobo
    Zhang, Xiaoyu
    Ming, Yu
    Zheng, Fei
    Zou, Jun
    JOURNAL OF ELECTRONIC MATERIALS, 2021, 50 (11) : 6337 - 6343
  • [7] Effect of hydrophobic silica aerogels in-situ on encapsulation the stability of CsPbBr3 quantum dots for white light-emitting diodes
    Xiong, Pan
    Gong, Yiqin
    Yang, Xiaoling
    Zhu, Yihua
    Chen, Cheng
    Shen, Jianhua
    JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 938 (938)
  • [8] Crown Ethers Enable Room-Temperature Et ILI Synthesis of CsPbBr3 Quantum Dots for Light-Emitting Diodes
    Veldhuis, Sjoerd A.
    Ng, Yan Fong
    Ahmad, Riyas
    Bruno, Annalisa
    Jamaludin, Nur Fadilah
    Damodaran, Bahulayan
    Mathews, Nripan
    Mhaisalkar, Subodh G.
    ACS ENERGY LETTERS, 2018, 3 (03): : 526 - 531
  • [9] Mesoporous silica-coated CsPbBr3:ZnBr2:NaBr nanocrystals with high photoluminescence and tunable wavelengths for micro light-emitting diodes
    Huang, Hai
    Yin, Shengnan
    Fu, Zhengbo
    Cao, Chunyan
    Zhang, Ruidan
    Chen, Daqin
    Xie, An
    JOURNAL OF MATERIALS CHEMISTRY C, 2025,
  • [10] Stable silica coated DDAB-CsPbX3 quantum dots and their application for white light-emitting diodes
    Zhu, Liang
    Wu, Chunxia
    Riaz, Saba
    Dai, Jun
    JOURNAL OF LUMINESCENCE, 2021, 233