Catalytic ketonization over oxide catalysts, part IV. Cycloketonization of diethyl hexanodiate

被引：17

作者：

Glinski, M ^{[1
]}

Kaszubski, M ^{[1
]}

机构：

[1] Warsaw Univ Technol Politech, Fac Chem, Catalyt Synth Lab, PL-00664 Warsaw, Poland

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2000年 / 70卷 / 02期

关键词：

ketonization of esters; diethyl adipate; cyclopentanone; manganese and cerium oxide catalysts;

D O I：

10.1023/A:1010332714901

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Activity of 20 wt.% MO2/S catalysts, where M = Mn, Ce and Th, and S = Al2O3 or SiO2, has been studied in cycloketonization of diethyl hexanodiate at the temperature range 573-698 K in a flow system. Only moderate yields of cyclopentanone (<35%) were achieved. The highest yields of ketone were obtained over MnO2/Al2O3 and MnO2/SiO2 catalysts - 33 and 27%, respectively. ThO2 containing catalysts were the most active, whereby ester transformations were detected below 573 K. In the presence of all catalysts the formation of the main product was accompanied by various amounts of 2-ethylcyclopentanone, cyclopent-2-en-1-one, cyclopentene, 2-cyclopentylidenecyclopentanone and numerous unidentified by-products.

引用

页码：271 / 274

页数：4

共 3 条

[1] Catalytic Ketonization over Oxide Catalysts, Part IV. Cycloketonization of Diethyl Hexanodiate
Marek Gliński
Michał Kaszubski
Reaction Kinetics and Catalysis Letters, 2000, 70 : 271 - 274
[2] Catalytic ketonization over oxide catalysts, Part VI.a Cross-ketonization of aliphatic and aromatic esters
Marek Gliński
Jaroslaw Szudybill
Reaction Kinetics and Catalysis Letters, 2002, 77 : 335 - 340
[3] Catalytic ketonization over oxide catalysts, part VI. Cross-ketonization of aliphatic and aromatic esters
Glinski, M
Szudybill, J
REACTION KINETICS AND CATALYSIS LETTERS, 2002, 77 (02): : 335 - 340

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