N′-benzoyl-N-p-bromophenylthiourea

被引：14

作者：

Yamin, BM ^{[1
]}

Yusof, MSM ^{[1
]}

机构：

[1] Univ Kebangsaan Malaysia, Sch Chem Sci & Food Technol, Bangi 43600, Selangor, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803003453

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C14H11BrN2OS, the bromophenyl and benzoyl groups lie cis and trans, respectively, to the S atom across the thiourea C-N bonds. Owing to the presence of the Br atom in the para position, the dihedral angle between the bromophenyl group and the central carbonylthiourea plane is increased to 20.40 (11)degrees, in comparison with 7.52 (9)degrees in its unsubstituted phenyl analogue. The molecules are linked by intermolecular contacts N-H...S and C-H...O to form linear chains parallel to the a axis.

引用

页码：O340 / O341

页数：2

共 9 条

[1] [Anonymous], 1996, SMART SAINT
[2] Synthesis and structures of two N,N′-bis(2-pyridinyl)thioureas and N-(2-pyridinyl)-N′-(benzoyl)thiourea
Kaminsky, W
Goldberg, KI
West, DX
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2002, 605 (01) : 9 - 15
[3] Nardelli M., 1995, J APPL CRYSTALLOGR, V28, P659, DOI [10.1107/S0021889895007138, DOI 10.1107/S0021889895007138]
[4] Raj SSS, 1999, ACTA CRYSTALLOGR C, V55, P1318
[5] Sheldrick G.M., 1996, SADABS VERSION 2008
[6] Sheldrick G.M., 1997, SHELXTL VERSION 5 1
[7] Spek A., 1990, ACTA CRYSTALLOGR, V46
[8] N-Benzoyl-N′-(2,6-dimethylphenyl)thiourea
Usman, A
Razak, IA
Satar, S
Kadir, MA
Yamin, BM
Fun, HK
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2002, 58 : O656 - O658
[9] N-Benzoyl-N′-phenylthiourea
Yamin, BM
Yusof, MSM
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2003, 59 : O151 - O152

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