Aerobic Liquid-Phase Oxidation of Para-tert-Butylcumene to Hydroperoxide

被引：2

作者：

Yarkina, E. M. ^{[1
]}

Kurganova, E. A. ^{[1
]}

Frolov, A. S. ^{[1
]}

Lebedeva, N., V ^{[1
]}

Koshel', G. N. ^{[1
]}

机构：

[1] Yaroslavl State Tech Univ, Yaroslavl 150000, Russia

来源：

PETROLEUM CHEMISTRY | 2019年 / 59卷 / 11期

关键词：

N-hydroxyphthalimide; hydroperoxide; oxidation; para-tert-butylcumene; para-tert-butylphenol;

D O I：

10.1134/S0965544119110161

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of aerobic liquid-phase oxidation of para-tert-butylcumene (PTBC) in the presence of N-hydroxyphthalimide has been studied. It has been found that the selectivity for the tertiary hydroperoxide of PTBC is over 95-98% up to a hydrocarbon conversion of 35-50%. The reasonability of the use of this reaction in the process of joint production of PTBC and acetone is shown. The mechanism of the process is discussed.

引用

页码：1245 / 1248

页数：4

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