Multi-element (13C, 2H and 34S) bulk and compound-specific stable isotope analysis for authentication of Allium species essential oils

被引:10
作者
Cuchet, Aurelien [1 ,2 ]
Anchisi, Anthony [2 ]
Telouk, Philippe [3 ]
Yao, Yijiao [3 ]
Schiets, Frederic [2 ]
Fourel, Francois [4 ]
Clement, Yohann [2 ]
Lanteri, Pierre [2 ]
Carenini, Elise [1 ]
Jame, Patrick [2 ]
Casabianca, Herve [2 ]
机构
[1] Albert Vieille SAS, 629 Route Grasse, F-06220 Vallauris, France
[2] Univ Claude Bernard Lyon 1, Univ Lyon, Inst Sci Analyt, CNRS,UMR 5280, 5 Rue La Doua, F-69100 Villeurbanne, France
[3] Univ Lyon, LGL TPE, CNRS, UCBL,ENSL, F-69364 Lyon, France
[4] Univ Claude Bernard Lyon 1, Univ Lyon, ENTPE, CNRS,UMR 5023,LEHNA, F-69622 Villeurbanne, France
关键词
Allium essential oil; Authentication; Multicollector-inductively coupled plasma; mass spectrometry; Isotope ratio mass spectrometry; GEOGRAPHICAL ORIGIN; RATIO ANALYSIS; SATIVUM L; SULFUR; ONION; ORGANOSULFIDES; FRACTIONATION; SULFATE;
D O I
10.1016/j.foodcont.2021.108086
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Pure and natural essential oils of Allium species are primarily used in the food industry, but due to their low yield, production quantities can be difficult to achieve and thus can be highly expensive. Due to these problems, adulterations are a reality in this field. The purpose of this research is to develop a multi element stable isotope analysis methodology for authentication of the essential oils of leek, onion, shallot, and chive. Naturalness of these essential oils was achieved by assessment of compound specific 813C and 834S: an addition of 5% of synthetic compound can be detected. Chemometric models were undertaken to assess purity by distinction of the Allium samples according to their species origin using bulk stable and compound specific 813C, 82H, 834S, and compositions of their major metabolites dipropyl disulfide, dipropyl trisulfide, methyl propyl disulfide, and methyl propyl trisulfide.
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页数:9
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