Rapid Characterization of Triterpene Saponins from Zornia brasiliensis by HPLC-ESI-MS/MS

被引：12

作者：

Nascimento, Yuri Mangueira ^{[1
]}

Abreu, Lucas Silva ^{[1
]}

Lima, Ramon Leal ^{[1
]}

Costa, Vicente Carlos O. ^{[1
]}

Miranda de Melo, Jose Iranildo ^{[2
]}

Braz-Filho, Raimundo ^{[3
]}

Silva, Marcelo Sobral ^{[1
]}

Tavares, Josean Fechine ^{[1
]}

机构：

[1] Univ Fed Paraiba, Grad Program Nat & Synthet Bioact Prod, Hlth Sci Ctr, BR-58051900 Joao Pessoa, Paraiba, Brazil

[2] Ctr Biol & Hlth Sci, Grad Program Ecol & Conservat, Dept Biol, BR-58429500 Campina Grande, Paraiba, Brazil

[3] Darcy Ribeiro Norte Fluminense State Univ, Ctr Sci & Technol, BR-28013600 Rio De Janeiro, Brazil

来源：

MOLECULES | 2019年 / 24卷 / 14期

关键词：

triterpene saponins; soyasaponins; Zornia brasiliensis; HPLC-DAD-ESI-MS; MS; PERFORMANCE LIQUID-CHROMATOGRAPHY; WISTARIA-BRACHYBOTRYS SIEB; LEGUMINOUS PLANTS; SOYASAPOGENOL-A; ESSENTIAL OIL; SOYASAPONINS; QUANTIFICATION; CONSTITUENTS; GLYCOSIDES; ISOFLAVONES;

D O I：

10.3390/molecules24142519

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Zornia brasiliensis Vogel (Leguminosae) is a species popularly known in Brazil as urinaria, urinana, and carrapicho, it is popularly used as a diuretic and in the treatment of venereal diseases. A specific methodology to obtain a saponin-enriched fraction and high-performance liquid chromatography coupled with diode array detection, ion trap mass spectrometry, and TOF-MS (HPLC-DAD-ESI-MS/MS) was applied for the analysis of triterpene saponins. The MS and MS/MS experiments were carried out by ionization in negative mode. Molecular mass and fragmentation data were used to support the structural characterization of the saponins. Based on retention times, high-resolution mass determination and fragmentation, 35 oleanane-triterpene saponins were tentatively identified in Z. brasiliensis.

引用

页数：14

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