Rapid Characterization of Triterpene Saponins from Zornia brasiliensis by HPLC-ESI-MS/MS

被引：12
|
作者：
Nascimento, Yuri Mangueira [1 ]
Abreu, Lucas Silva [1 ]
Lima, Ramon Leal [1 ]
Costa, Vicente Carlos O. [1 ]
Miranda de Melo, Jose Iranildo [2 ]
Braz-Filho, Raimundo [3 ]
Silva, Marcelo Sobral [1 ]
Tavares, Josean Fechine [1 ]
机构：
[1] Univ Fed Paraiba, Grad Program Nat & Synthet Bioact Prod, Hlth Sci Ctr, BR-58051900 Joao Pessoa, Paraiba, Brazil
[2] Ctr Biol & Hlth Sci, Grad Program Ecol & Conservat, Dept Biol, BR-58429500 Campina Grande, Paraiba, Brazil
[3] Darcy Ribeiro Norte Fluminense State Univ, Ctr Sci & Technol, BR-28013600 Rio De Janeiro, Brazil
来源：
MOLECULES | 2019年 / 24卷 / 14期
关键词：
triterpene saponins; soyasaponins; Zornia brasiliensis; HPLC-DAD-ESI-MS; MS; PERFORMANCE LIQUID-CHROMATOGRAPHY; WISTARIA-BRACHYBOTRYS SIEB; LEGUMINOUS PLANTS; SOYASAPOGENOL-A; ESSENTIAL OIL; SOYASAPONINS; QUANTIFICATION; CONSTITUENTS; GLYCOSIDES; ISOFLAVONES;
D O I：
10.3390/molecules24142519
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Zornia brasiliensis Vogel (Leguminosae) is a species popularly known in Brazil as urinaria, urinana, and carrapicho, it is popularly used as a diuretic and in the treatment of venereal diseases. A specific methodology to obtain a saponin-enriched fraction and high-performance liquid chromatography coupled with diode array detection, ion trap mass spectrometry, and TOF-MS (HPLC-DAD-ESI-MS/MS) was applied for the analysis of triterpene saponins. The MS and MS/MS experiments were carried out by ionization in negative mode. Molecular mass and fragmentation data were used to support the structural characterization of the saponins. Based on retention times, high-resolution mass determination and fragmentation, 35 oleanane-triterpene saponins were tentatively identified in Z. brasiliensis.
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收藏
页数：14
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