Simultaneous flow enhancement of high-filled polyamide 66/glass fiber composites

被引:11
作者
Choi, Hwan Seok [1 ]
Lim, Dohyun [1 ,2 ]
Kim, Dong-Gyun [1 ]
Kim, Byoung Gak [1 ]
Kim, Yong Seok [1 ]
Lee, Sung-Goo [1 ]
Kim, Sang Gu [3 ]
Park, Byung Wook [3 ]
Seo, Kwan Ho [4 ]
Yoon, Ho Gyu [2 ]
Yoo, Youngjae [1 ]
机构
[1] Korea Res Inst Chem Technol, Adv Mat Div, Daejeon 34114, South Korea
[2] Korea Univ, Dept Mat Sci & Engn, Seoul 02841, South Korea
[3] Woosung Chem Co Ltd, Youngcheon 38906, Gyeongsangbuk D, South Korea
[4] Kyungpook Natl Univ, Dept Polymer Sci, Daegu 41566, South Korea
关键词
Composites; Flow modifiers; Flowability; MECHANICAL-PROPERTIES; G-MA; NANOCOMPOSITES; MORPHOLOGY; BEHAVIOR; TENSILE; COPOLYMERS;
D O I
10.1016/j.jallcom.2017.06.146
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, we investigated the effects of the flow modifier addition on the rheological behavior and mechanical properties of high-filled polyamide 66 composites prepared from melt compounding. The flow modifiers were prepared from various amine monomers and fatty acids, and their structures were analyzed by Fourier transform infrared spectroscopy. The synthesized flow modifiers were added simultaneously during melt compounding. The presence of flow modifiers significantly reduced torque in neat polyamide 66 polymer and glass fiber-reinforced polyamide 66 composites, respectively, while the torque during compounding in composites with glass fiber contents of 50 wt% has decreased by approximately 12% after the addition of 1 phr of hexamethylene bis-stearamide indicating the simultaneous enhancement in flowability. The presence of the synthesized flow modifiers in matrix polymers improves flowability of the composites during injection molding without compromising the mechanical properties. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:628 / 636
页数:9
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