Living radical polymerization of MMA in the presence of piperidino-dithiocarbamate derivatives as photoiniferters

被引：11

作者：

Bertin, D

Boutevin, B

Gramain, P

Fabre, JM

Montginoul, C

机构：

[1] Ecole Natl Super Chim Montpellier, UPRES A50760, Lab Chim Appl, F-34053 Montpellier 1, France

[2] Univ Montpellier 2, UPRES A50760, Lab Chim Struct Organ, F-34095 Montpellier, France

来源：

EUROPEAN POLYMER JOURNAL | 1998年 / 34卷 / 01期

关键词：

D O I：

10.1016/S0014-3057(97)00059-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Radical polymerizations of methyl methacrylate were carried out in the presence of photoiniferters (RDC) containing a piperidino-dithiocarbamate group. The effects of the structure of the RDC on the photopolymerization in the presence or absence of a transfer agent such as tetraethylthiuram disulfide (TD) were investigated. The influence of the presence of a transfer agent (TD) on the living character and the control of the polymerization were also discussed. (C) 1997 Elsevier Science Ltd.

引用

页码：85 / 90

页数：6

共 12 条

[1]

BANDRUP J., 1989, POLYM HDB

[2] SYNTHESIS OF ORGANIC CONDUCTOR TETRAMETHYLTETRASELENOFULVALENIUM 7,7,8,8-TETRACYANO-PARA-QUINODIMETHANIDE (TMTSF-TCNQ) [4,4',5,5'-TETRAMETHYL-DELTA2,2'-BIS-1,3-DISELENOLIUM 3,6-BIS-(DICYANOMETHYLENE)CYCLOHEXADIENIDE] [J].