Production of controlled architectures of aligned carbon nanotubes by an injection chemical vapour deposition method

被引:393
作者
Singh, C [1 ]
Shaffer, MS [1 ]
Windle, AH [1 ]
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
关键词
carbon nanotubes; chemical vapour deposition; electron microscopy; Raman spectroscopy;
D O I
10.1016/S0008-6223(02)00314-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High purity, aligned multi-wall carbon nanotube films were grown on quartz substrates by injecting a solution of ferrocene in toluene into a suitable reaction furnace. The injection CVD method allows excellent control of the catalyst to carbon ratio. The detailed study presented here demonstrates how such a system can be used to control the nanotube diameter, length, alignment and yield by manipulating the experimental parameters. Primary growth was found to occur via a base growth mechanism, although overgrowths of single wall carbon nanotubes were obtained under certain conditions. Such a method also allows nanotubes of various packing densities to be produced which may be useful for specific applications such as electrodes. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:359 / 368
页数:10
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