Effects of blending on surface characteristics of copper corrosion products in drinking water distribution systems

被引：33
作者：
Xiao, Weizhong
Hong, Seungkwan
Tang, Zhijian
Seal, Sudipta
Taylor, James S.
机构：
[1] Korea Univ, Dept Civil & Environm Engn, Seoul 136701, South Korea
[2] ZFI, Water Engn & Sci, Orlando, FL 32826 USA
[3] Penn State Harrisburg, Environm Engn, Middletown, PA 17057 USA
[4] Univ Cent Florida, Adv Mat Proc & Anal Ctr, Orlando, FL 32816 USA
[5] Univ Cent Florida, Nanosci & Technol Ctr, NSTC, Orlando, FL 32816 USA
[6] Univ Cent Florida, Dept Civil & Environm Engn, Orlando, FL 32816 USA
来源：
CORROSION SCIENCE | 2007年 / 49卷 / 02期
关键词：
copper; modelling studies; XPS; XRD; corrosion potential;
D O I：
10.1016/j.corsci.2006.04.018
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Copper scales formed over 6-months during exposure to ground, surface and saline waters were characterized by EDS, XRD and XPS. Scale color and hardness were light red-brown-black/hard for high alkalinity and blue-green/soft for high SO4 or Cl waters. Cl was present in surface or saline copper scales. The Cu/Cu2O ratio decreased with time indicating an e transfer copper corrosion mechanism. Cu2O, CuO, and Cu(OH)(2) dominated the top 0.5-1 A degrees scale indicating continuous corrosion. Cu2O oxidation to CuO increased with alkalinity, and depended on time and pH. Total copper release was predicted using a Cu(OH)(2) model. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：449 / 468
页数：20
相关论文
共 22 条
  • [1] *AM WAT WORKS ASS, 1996, INT CORR WAT DISTR S
  • [2] *APHA AWWA WPCF, 1999, STAND METH EX WAT WA
  • [3] NATURE OF THE USE OF ADVENTITIOUS CARBON AS A BINDING-ENERGY STANDARD
    BARR, TL
    SEAL, S
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1995, 13 (03): : 1239 - 1246
  • [4] Copper corrosion in drinking water distribution systems - The influence of water quality
    Broo, AE
    Berghult, B
    Hedberg, T
    [J]. CORROSION SCIENCE, 1997, 39 (06) : 1119 - 1132
  • [5] Chalyi V, 1963, RUSS J INORG CHEM, V8, P269
  • [6] Surface characterization of artificial corrosion layers on copper alloy reference materials
    Constantinides, I
    Adriaens, A
    Adams, F
    [J]. APPLIED SURFACE SCIENCE, 2002, 189 (1-2) : 90 - 101
  • [7] Edwards M, 1996, J AM WATER WORKS ASS, V88, P81
  • [8] ON THE CORROSION OF COPPER IN PURE WATER
    ERIKSEN, TE
    NDALAMBA, P
    GRENTHE, I
    [J]. CORROSION SCIENCE, 1989, 29 (10) : 1241 - 1250
  • [9] Feitknecht W., 1963, Pure Appl. Chem, V6, P130
  • [10] The corrosion behaviour of copper in neutral tap water .1. Corrosion mechanisms
    Feng, Y
    Teo, WK
    Siow, KS
    Tan, KL
    Hsieh, AK
    [J]. CORROSION SCIENCE, 1996, 38 (03) : 369 - 385
123