Tunable luminescence of Dy3+ single-doped and Dy3+/Tm3+ co-doped tungsten borate glasses

被引:32
作者
Hu, J. [1 ,2 ]
Gong, X. H. [2 ]
Chen, Y. J. [2 ]
Huang, J. H. [2 ]
Lin, Y. F. [2 ]
Luo, Z. D. [2 ]
Huang, Y. D. [2 ]
机构
[1] Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
关键词
Dy3+ single-doped; Dy3+/Tm3+ co-doped; Tungsten borate glass; Luminescence; WHITE-LIGHT EMISSION; OPTICAL-PROPERTIES; PHOTOLUMINESCENCE PROPERTIES; TELLURITE GLASSES; EMITTING-DIODES; PHOSPHOR; EXCITATION; TRANSPARENT; LABWO6; COLOR;
D O I
10.1016/j.optmat.2014.09.034
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
RE3+ (RE3+ = Tm3+, Dy3+) ion single and co-doped tungsten borate glasses for white light emitting diodes (LEDs) were prepared by melt quenching method. Emission and excitation spectra of the glasses were measured. The color of luminescence can be tuned by changing the composition of glass matrix or the concentrations of Tm3+ and Dy3+ ions. White light emission can be achieved from 0.5 Dy3+ single-doped 15WO(3)-25La(2)O(3)-60B(2)O(3) and 0.4Tm(3+)/1.5Dy(3+) co-doped 50WO(3)-25La(2)O(3)-25B(2)O(3) glasses. In addition, energy transfers between Tm3+ and Dy3+ were also analyzed. The Dy3+/Tm3+ co-doped tungsten borate glasses may be potential candidates for white LED application. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:108 / 112
页数:5
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