SPEEK/Zeolite/Ionic-Liquid Anhydrous Polymer Membranes for Fuel-Cell Applications

被引：32

作者：

da Trindade, Leticia G. ^{[1
]}

Pereira, Ernesto C. ^{[1
]}

机构：

[1] Univ Fed Sao Carlos, Dept Chem, CP 676, BR-13560970 Sao Carlos, SP, Brazil

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 17期

基金：

巴西圣保罗研究基金会;

关键词：

Polymers; Zeolites; Ionic liquids; Fuel cells; PROTON-EXCHANGE MEMBRANES; POLY(ETHER ETHER KETONE); IONIC LIQUIDS; COMPOSITE MEMBRANES; ELECTROLYTE MEMBRANES; CONDUCTING MEMBRANES; 1-BUTYL-3-METHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE; ELECTROCHEMICAL PROPERTIES; TEMPERATURE; SPEEK;

D O I：

10.1002/ejic.201601559

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sulfonated poly(ether ether ketone) (SPEEK)/zeolite/ionic-liquid composite membranes were prepared with different amounts of 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([C4MI]CF3SO3) or 1-decyl-3-methylimidazolium trifluoromethanesulfonate ([C10MI]CF3SO3) ionic liquids (ILs). The structure of the composite membranes was investigated by FTIR-ATR spectroscopy, X-ray diffraction, atomic force microscopy, and by thermogravimetric analyses. The introduction of the IL, encapsulated in zeolite, into the SPEEK polymer leads to improvement of the water uptake, thermal stability, and proton conductivity of the composite membranes, compared with pristine SPEEK. The proton conductivity of the membranes with 1.5% and 2.0% [C4MI]CF3SO3 IL showed values of 3.34 mS cm(-1) and 5.98 mS cm(-1), respectively, under anhydrous conditions at 80 degrees C. The conductivity obtained for these membranes is about 100 times higher than for pristine SPEEK (0.038 mS cm(-1)).

引用

页码：2369 / 2376

页数：8

共 64 条

[1] Prospects of biodiesel production from vegetables oils in India [J].

Barnwal, BK ;

Sharma, MP .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2005, 9 (04) :363-378

[2] SYNTHESIS AND PROPERTIES OF POLY(ETHER ETHER KETONE) POLY(ETHER SULFONE) BLOCK-COPOLYMERS [J].

CAO, J ;

SU, WC ;

WU, ZW ;

KITAYAMA, T ;

HATADA, K .

POLYMER, 1994, 35 (16) :3549-3556

[3] A simple and practical method for the preparation and purity determination of halide-free imidazolium ionic liquids [J].

Cassol, CC ;

Ebeling, G ;

Ferrera, B ;

Dupont, J .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (1-2) :243-248

[4] Thermal analysis of γ-butyrolactone+1 butyl-3-methyl-imidazolium ionic liquids mixtures [J].

Chagnes, A ;

Allouchi, H ;

Carré, B ;

Lemordant, D .

SOLID STATE IONICS, 2005, 176 (15-16) :1419-1427

[5] Phosphoric acid doped high temperature proton exchange membranes based on sulfonated polyetheretherketone incorporated with ionic liquids [J].

Che, Quantong ;

He, Ronghuan ;

Yang, Jingshuai ;

Feng, Li ;

Savinell, Robert F. .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (05) :647-649

[6] Properties improvement of SPEEK based proton exchange membranes by doping of ionic liquids and Y2O3 [J].

Chen, Jianbin ;

Guo, Qiang ;

Li, Dan ;

Tong, Juying ;

Li, Xia .

PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2012, 22 (01) :26-30

[7] A review on non-precious metal electrocatalysts for PEM fuel cells [J].

Chen, Zhongwei ;

Higgins, Drew ;

Yu, Aiping ;

Zhang, Lei ;

Zhang, Jiujun .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3167-3192

[8] Enhancement of PEM fuel cell performance at higher temperatures and lower humidities by high performance membrane electrode assembly based on Nafion/zeolite membrane [J].

Devrim, Yilser ;

Albostan, Ayhan .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (44) :15328-15335

[9] Progress in the use of ionic liquids as electrolyte membranes in fuel cells [J].

Diaz, Mariana ;

Ortiz, Alfredo ;

Ortiz, Inmaculada .

JOURNAL OF MEMBRANE SCIENCE, 2014, 469 :379-396

[10] Comparison of homogeneously and heterogeneously sulfonated polyetheretherketone membranes in preparation, properties and cell performance [J].

Do, Khanh Ngan T. ;

Kim, Dukjoon .

JOURNAL OF POWER SOURCES, 2008, 185 (01) :63-69

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