Enhancement in dielectric and optical properties of La1-xCexFeO3 nanoparticles

被引:18
作者
Arman, M. M. [1 ]
El-Dek, S. I. [2 ]
机构
[1] Cairo Univ, Fac Sci, Dept Phys, Mat Sci Lab 1, Giza, Egypt
[2] Beni Suef Univ, Fac PSAS, Mat Sci & Nanotechnol Dept, Bani Suwayf, Egypt
来源
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T | 2019年 / 8卷 / 06期
关键词
Orthoferrite; LaFeO3; Dielectric; Optical properties; Perovskite; Nanoparticles; ELECTRICAL-PROPERTIES; PEROVSKITE OXIDES; LANTHANUM FERRITE; CO-SUBSTITUTION; SOL-GEL; LAFEO3; NANOFIBERS;
D O I
10.1016/j.jmrt.2019.09.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
La1-xCexFeO3; 0 <= x <= 0.15 nanoparticles were prepared in single phase using flash combustion technique. The crystalline structure and morphology of the investigated samples were researched through XRD and HRTEM. As a result, the dielectric constant of LaFeO3 was enhanced by Ce3+ ion substitution due to some the Ce3+ ions changes its valence to Ge4+ ions. The conduction mechanism in La1-xCexFeO3 samples is the small polaron (SP) tunneling. The type of optical transition is direct allowed transition and the band gap values are in the range of (2.8-1.89 eV). 8/ values of La0.90Ce0.10FeO3 decreases by increasing the external applied pressure at different frequencies. (C) 2019 The Authors. Published by Elsevier B.V.
引用
收藏
页码:5396 / 5404
页数:9
相关论文
共 29 条
[1]   Novel multiferroic La0.95Sb0.05FeO3 orthoferrite [J].
Ahmed, M. A. ;
Selim, M. Solyman ;
Arman, M. M. .
MATERIALS CHEMISTRY AND PHYSICS, 2011, 129 (03) :705-712
[2]  
[Anonymous], 2014, ADV APPL SCI RES
[3]   Role of A Cation Vacancy in the Exchange-Biased LaFeO3 Multiferroic Nanocrystals [J].
Arman, M. M. ;
Ahmed, M. A. ;
El-Dek, S. I. .
JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, 2018, 31 (06) :1867-1879
[4]   Effect of antimony substitution on structural and electrical properties of LaFeO3 [J].
Berchmans, L. John ;
Sindhu, R. ;
Angappan, S. ;
Augustin, C. O. .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2008, 207 (1-3) :301-306
[5]   The role of catalytic cobalt-modified lanthanum ferrite nano-crystals in selective sensing of carbon monoxide [J].
Bhargav, K. K. ;
Ram, S. ;
Majumder, S. B. .
JOURNAL OF MATERIALS SCIENCE, 2015, 50 (02) :644-651
[6]   Physics of the multi-functionality of lanthanum ferrite ceramics [J].
Bhargav, K. K. ;
Ram, S. ;
Majumder, S. B. .
JOURNAL OF APPLIED PHYSICS, 2014, 115 (20)
[7]   AC CONDUCTION IN AMORPHOUS-CHALCOGENIDE AND PNICTIDE SEMICONDUCTORS [J].
ELLIOTT, SR .
ADVANCES IN PHYSICS, 1987, 36 (02) :135-218
[8]   The laws of crystal chemistry [J].
Goldschmidt, VM .
NATURWISSENSCHAFTEN, 1926, 14 :477-485
[9]   Structural, magnetic and sensing properties of lanthanum ferrite via facile sol gel oxalate precursor route [J].
Hessien, M. M. ;
Mersal, Gaber A. M. ;
Mohsen, Q. ;
Alosaimi, Dlayel .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (05) :4170-4178
[10]   Magnetic entropy change and magnetotransport in Gd doped La-Sr-Mn-O perovskite [J].
Huang, SL ;
Cui, XG ;
Wang, DH ;
Han, ZD ;
Du, YW .
JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 398 (1-2) :184-187