Asymmetric Organocatalysis in Deep Eutectic Solvents

被引：40

作者：

Alonso, Diego A. ^{[1
,2
]}

Burlingham, Sarah-Jayne ^{[1
,2
]}

Chinchilla, Rafael ^{[1
,2
]}

Guillena, Gabriela ^{[1
,2
]}

Ramon, Diego J. ^{[1
,2
]}

Tiecco, Matteo ^{[3
]}

机构：

[1] Alicante Univ, Dept Organ Chem, POB 99, Alicante 03080, Spain

[2] Alicante Univ, Inst Organ Synth, POB 99, Alicante 03080, Spain

[3] Univ Perugia, Dept Chem Biol & Biotechnol, Via Elce Sotto 8, I-06124 Perugia, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 2021卷 / 29期

关键词：

Active solvents; Asymmetric organocatalysis; Deep eutectic solvents; Enantioselectivity; Green chemistry; CHIRAL IONIC LIQUIDS; 1,3-DICARBONYL COMPOUNDS; CONJUGATE ADDITION; MICHAEL ADDITION; REACTION MEDIA; MALEIMIDES; 2-AMINOBENZIMIDAZOLES; ALDEHYDES; MIXTURES;

D O I：

10.1002/ejoc.202100385

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The recent advances in asymmetric organocatalysis using eutectic mixtures as a reaction medium are revised in this mini-review. In addition, the first enantioselective transformations using chiral eutectic solvents, which play the role of a green medium and organocatalyst, are described. In this minireview we intend to deepen not only in the synthetic aspects of asymmetric organocatalysis in eutectic mixtures, but also in the fundamental issues that seem to be essential for a successful development of this promising, and at the same time challenging, methodology.

引用

页码：4065 / 4071

页数：7

共 32 条

[1] Chiral 2-Aminobenzimidazoles as Recoverable Organocatalysts for the Addition of 1,3-Dicarbonyl Compounds to Nitroalkenes
Almasi, Diana
Alonso, Diego A.
Gomez-Bengoa, Enrique
Najera, Carmen
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (16) : 6163 - 6168
[2] Recent Advances in Asymmetric Organocatalyzed Conjugate Additions to Nitroalkenes
Alonso, Diego A.
Baeza, Alejandro
Chinchilla, Rafael
Gomez, Cecilia
Guillena, Gabriela
Pastor, Isidro M.
Ramon, Diego J.
[J]. MOLECULES, 2017, 22 (06):
[3] Inelastic neutron scattering study of reline: shedding light on the hydrogen bonding network of deep eutectic solvents
Araujo, C. F.
Coutinho, J. A. P.
Nolasco, M. M.
Parker, S. F.
Ribeiro-Claro, P. J. A.
Rudic, S.
Soares, B. I. G.
Vaz, P. D.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (27) : 17998 - 18009
[4] Chiral ionic liquids, a renewal for the chemistry of chiral solvents?: Design, synthesis and applications for chiral recognition and asymmetric synthesis
Baudequin, C
Brégeon, D
Levillain, J
Guillen, F
Plaquevent, JC
Gaumont, AC
[J]. TETRAHEDRON-ASYMMETRY, 2005, 16 (24) : 3921 - 3945
[5] Berkessel A, 2005, ASYMMETRIC ORGANOCATALYSIS: FROM BIOMIMETIC CONCEPTS TO APPLICATIONS IN ASYMMETRIC SYNTHESIS, P1, DOI 10.1002/3527604677
[6] Applications of chiral ionic liquids
Bica, Katharina
Gaertner, Peter
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (19) : 3235 - 3250
[7] Towards the development of continuous, organocatalytic, and stereoselective reactions in deep eutectic solvents
Brenna, Davide
Massolo, Elisabetta
Puglisi, Alessandra
Rossi, Sergio
Celentano, Giuseppe
Benaglia, Maurizio
Capriati, Vito
[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2016, 12 : 2620 - 2626
[8] Dalko P.I., 2007, ENANTIOSELECTIVE ORG
[9] Chiral ionic liquids: Synthesis and applications
Ding, J
Armstrong, DW
[J]. CHIRALITY, 2005, 17 (05) : 281 - 292
[10] Dominguez de Maria P, 2015, SUSTAIN CHEM PROCESS, V3, P12, DOI DOI 10.1186/S40508-015-0039-0

← 1 2 3 4 →