Highly sensitive and selective detection of picric acid using a one pot biomolecule inspired polyindole/CdS nanocomposite

被引：31
作者：
Faraz, Mohd [1 ,2 ]
Shakir, Mohammad [1 ]
Khare, Neeraj [2 ]
机构：
[1] Aligarh Muslim Univ, Dept Chem, Aligarh 202002, Uttar Pradesh, India
[2] Indian Inst Technol Delhi, Dept Phys, New Delhi 110016, India
来源：
NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 13期
关键词：
ULTRASENSITIVE DETECTION; COFE2O4; NANOPARTICLES; ZNO NANOPARTICLES; AQUEOUS-MEDIA; EXPLOSIVES; POLYMERIZATION; PERFORMANCE; COMPOSITE; CHEMOSENSORS; POLYMERS;
D O I：
10.1039/c7nj01132f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Picric acid is very dangerous environmental pollutant generated from leather, chemical and dye industries due to its high toxicity. Therefore, efforts have been made to develop techniques for the efficient detection of picric acid. A new and novel biomolecule inspired polyindole/CdS (PIN/CdS) nanocomposite has been synthesized by an in situ chemical polymerization method for the detection of picric acid in organic medium. The PIN/CdS nanocomposite was characterized by means of Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Energy dispersive X-ray (EDAX), ultraviolet-visible (UV-Vis) and fluorescence spectroscopy, in order to evaluate its optical properties, particles size distribution and morphology. The synthesized nanocomposite shows remarkably high sensitivity and selectivity towards picric acid, compared to the other organic compounds like aniline, benzoic acid, nitrobenzene, benzamide and nitromethane. The Stern-Volmer constant (K-SV) value was found to be 30 x 10(3) M-1 for the detection of picric acid, confirming very high sensitivity of the PIN/CdS nanocomposite for picric acid.
引用
收藏
页码：5784 / 5793
页数：10
相关论文
共 57 条
[11]   Synthesis and Characterization of Polypyrrole/Graphite Oxide Composite by In Situ Emulsion Polymerization [J].
Gu, Zheming ;
Li, Chunzhong ;
Wang, Gengchao ;
Zhang, Ling ;
Li, Xiaohui ;
Wang, Wendong ;
Jin, Shilei .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2010, 48 (12) :1329-1335
[12]   A novel picric acid film sensor via combination of the surface enrichment effect of chitosan films and the aggregation-induced emission effect of siloles [J].
He, Gang ;
Peng, Haonan ;
Liu, Taihong ;
Yang, Meini ;
Zhang, Yuan ;
Fang, Yu .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (39) :7347-7353
[13]   Electropolymerization of Polypyrrole and Polypyrrole-ZnO Nanocomposites on Mild Steel and Its Corrosion Protection Performance [J].
Hosseini, M. G. ;
Bagheri, R. ;
Najjar, R. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 121 (06) :3159-3166
[14]   A cationic iridium(III) complex with aggregation-induced emission (AIE) properties for highly selective detection of explosives [J].
Hou, Xue-Gang ;
Wu, Yong ;
Cao, Hong-Tao ;
Sun, Hai-Zhu ;
Li, Hai-Bin ;
Shan, Guo-Gang ;
Su, Zhong-Min .
CHEMICAL COMMUNICATIONS, 2014, 50 (45) :6031-6034
[15]   Ultrasensitive detection of nitroexplosive - picric acid via a conjugated polyelectrolyte in aqueous media and solid support [J].
Hussain, Sameer ;
Malik, Akhtar Hussain ;
Afroz, Mohammad Adil ;
Iyer, Parameswar Krishnan .
CHEMICAL COMMUNICATIONS, 2015, 51 (33) :7207-7210
[16]   Nanocomposites Derived from Polymers and Inorganic Nanoparticles [J].
Jeon, In-Yup ;
Baek, Jong-Beom .
MATERIALS, 2010, 3 (06) :3654-3674
[17]   Nitroaromatic Compounds, from Synthesis to Biodegradation [J].
Ju, Kou-San ;
Parales, Rebecca E. .
MICROBIOLOGY AND MOLECULAR BIOLOGY REVIEWS, 2010, 74 (02) :250-+
[18]   Electrical and Dielectric Properties of Polyaniline Doped with Carboxyl-Functionalized Multiwalled Carbon Nanotube [J].
Kar, Pradip ;
Choudhury, Arup .
ADVANCES IN POLYMER TECHNOLOGY, 2013, 32 :E760-E770
[19]   Attogram Sensing of Trinitrotoluene with a Self-Assembled Molecular Gelator [J].
Kartha, Kalathil K. ;
Babu, Sukumaran S. ;
Srinivasan, Sampath ;
Ajayaghosh, Ayyappanpillai .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (10) :4834-4841
[20]   Synthesis by in situ chemical oxidative polymerization and characterization of polyaniline/iron oxide nanoparticle composite [J].
Khan, Aslam ;
Aldwayyan, Abdullah S. ;
Alhoshan, Mansour ;
Alsalhi, Mohamad .
POLYMER INTERNATIONAL, 2010, 59 (12) :1690-1694
123456