Strong Infrared Nonlinear Optical Efficiency and High Laser Damage Threshold Realized in Quaternary Alkali Metal Sulfides Na2Ga2MS6 (M = Ge, Sn) Containing Mixed Nonlinear Optically Active Motifs

被引：42

作者：

Li, Shu-Fang ^{[1
]}

Jiang, Xiao-Ming ^{[1
]}

Liu, Bin-Wen ^{[1
]}

Yan, Dong ^{[1
]}

Zeng, Hui-Yi ^{[1
]}

Guo, Guo-Cong ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 12期

基金：

中国博士后科学基金;

关键词：

DIAMOND-LIKE SEMICONDUCTORS; 2ND-HARMONIC GENERATION; PARAMETRIC AMPLIFICATION; SINGLE-CRYSTALS; MID-IR; M-IV; SE; AGGAS2; SI; PERFORMANCES;

D O I：

10.1021/acs.inorgchem.8b00891

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new infrared (IR) nonlinear optical (NLO) sulfides, Na2Ga2GeS6 and Na2Ga2GeS6 , were obtained by mixing different typical NLO-active motifs GaS4 and GeS4/SnS4 in the alkali metal-containing system. The IR NLO sulfides present laser-induced damage thresholds that are 18.1 and 17.9 times that of the reference AgGaS2 (AGS) and second-harmonic generation efficiencies that are 0.8 and 1.1 times that of AGS. These properties originate from the GaS4, GeS4, and SnS4 tetrahedral blocks in the structures of the sulfides. Both compounds also exhibit a broad transparency range and type-I phase-matching behavior, which support their high potential in high-power laser applications. This work sheds new light on the development of promising mid-IR NLO materials by combining different NLO-active motifs.

引用

页码：6783 / 6786

页数：4

共 30 条

[1] Analysis of the Laser Damage Characteristics of a Production Lot [J].

Arenberg, Jonathan W. ;

Jensen, Lars O. ;

Ristau, Detlev .

LASER-INDUCED DAMAGE IN OPTICAL MATERIALS: 2014, 2014, 9237

[2] SILVER THIOGALLATE AND RELATED DIAMOND-LIKE SEMICONDUCTORS FOR NONLINEAR-OPTICAL LASER DEVICES [J].

BHAR, GC .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1993, 32 :653-659

[3] X-RAY STUDY OF THE THERMAL-EXPANSION ANISOTROPY IN AGGAS2 AND AGINS2 COMPOUNDS OVER THE TEMPERATURE-RANGE FROM 80 TO 650-K [J].

BODNAR, IV ;

ORLOVA, NS .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1985, 91 (02) :503-507

[4] LINEAR AND NONLINEAR OPTICAL PROPERTIES OF ZNGEP2 AND CDSE [J].

BOYD, GD ;

BUEHLER, E ;

STORZ, FG .

APPLIED PHYSICS LETTERS, 1971, 18 (07) :301-&

[5] Growth of AgGaS2 single crystals by modified furnace [J].

Chen, Baojun ;

Zhu, Shifu ;

Zhao, Beijun ;

Zhang, Jianjun ;

Huang, Yi ;

Li, Ming ;

Liu, Juan ;

Tan, Bo ;

Wang, Ruilin ;

He, Zhiyu .

JOURNAL OF CRYSTAL GROWTH, 2006, 292 (02) :490-493

[6] First principles methods using CASTEP [J].

Clark, SJ ;

Segall, MD ;

Pickard, CJ ;

Hasnip, PJ ;

Probert, MJ ;

Refson, K ;

Payne, MC .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2005, 220 (5-6) :567-570

[7] Ternary chalcogenides LiBC2 (B = In, Ga; C=S, Se, Te) for mid-IR nonlinear optics [J].

Isaenko, L. ;

Yelisseyev, A. ;

Lobanov, S. ;

Krinitsin, P. ;

Petrov, V. ;

Zondy, J. -J. .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2006, 352 (23-25) :2439-2443

[8] A POWDER TECHNIQUE FOR EVALUATION OF NONLINEAR OPTICAL MATERIALS [J].

KURTZ, SK ;

PERRY, TT .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1968, QE 4 (05) :333-+

[9] Na2ZnGe2S6: A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold [J].

Li, Guangmao ;

Wu, Kui ;

Liu, Qiong ;

Yang, Zhihua ;

Pan, Shilie .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (23) :7422-7428

[10] Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser Induced Damage Thresholds [J].

Li, Shu-Fang ;

Jiang, Xiao-Ming ;

Liu, Bin-Wen ;

Yan, Dong ;

Lin, Chen-Sheng ;

Zeng, Hui-Yi ;

Guo, Guo-Cong .

CHEMISTRY OF MATERIALS, 2017, 29 (04) :1796-1804

← 1 2 3 →