Bulk metallic glass formation of Cu-Zr-Ti-Sn alloys

被引:79
|
作者
Zhang, QS [1 ]
Zhang, HF [1 ]
Deng, YF [1 ]
Ding, BZ [1 ]
Hu, ZQ [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
关键词
casting; metallic glass; copper alloys; glass-forming ability;
D O I
10.1016/S1359-6462(03)00285-9
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Cu-Zr-Ti-Sn bulk metallic glasses were produced by copper mold casting. The effects of Sn addition on glass-forming ability (GFA), thermal stability of the Cu60Zr30Ti10 bulk metallic glass were investigated. It was found that a bulk metallic glass of 5 mm in diameter was prepared in a (Cu60Zr30Ti10)(99)Sn-1 alloy by copper mold casting. The addition of 1 at.% Sn is effective for an increase in GFA. The DeltaT(x) and T-g/T-I are 46 K and 0.63, respectively, for (Cu60Zr30Ti10)(99)Sn-1 alloy. With increasing the content of Sn, the value of TITI increases, but the alloys begin to lose bulk metallic GFA. The new parameter gamma has a better correlation with the GFA of the Cu-based alloys. (C) 2003 Published by Elsevier Science Ltd. on behalf of Acta Materialia Inc.
引用
收藏
页码:273 / 278
页数:6
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