Revisiting mechanisms to inhibit Ag3Sn plates in Sn-Ag-Cu solders with 1 wt.% Zn addition

被引:40
作者
Luo, Z. -B. [1 ]
Zhao, J. [1 ]
Gao, Y. -J. [1 ]
Wang, L. [1 ]
机构
[1] Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
关键词
Sn-Ag-Cu; Zn; Ag3Sn; (Cu; Ag)(5)Zn-8; Cooling rate; INTERMETALLIC COMPOUNDS; LEAD-FREE; ALLOYS; SOLIDIFICATION; INTERFACE; GROWTH; BEHAVIOR; JOINTS;
D O I
10.1016/j.jallcom.2010.03.191
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two mechanisms to inhibit Ag3Sn plates were discovered in Sn-1.0Ag-0.5Cu and Sn-3.0Ag-0.5Cu with 1 wt.% Zn addition. It was revealed that 1 wt.% Zn not only reduced the supercooling of beta-Sn, but also promoted the formation of gamma-(Cu,Ag)(5)Zn-8 compounds. The amount of gamma-(Cu,Ag)(5)Zn-8 was larger in Sn-3.0Ag-0.5Cu than that in Sn-1.0Ag-0.5Cu. Meanwhile, the Ag content in gamma-(Cu,Ag)(5)Zn-8 was higher in the high-Ag solder. Although more gamma particles formed under slow cooling rate, the Ag content varied a little with cooling rate. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:39 / 45
页数:7
相关论文
共 23 条
  • [1] Mechanical property and fracture behavior characterizations of 96.5 Sn-3.0 Ag-0.5 Cu solder joints
    Chang, Shou-Yi
    Huang, Yi-Chung
    Lin, Yu-Mu
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 490 (1-2) : 508 - 514
  • [2] Microstructural evolution of intermetallic compounds in Sn-3.5Ag-X (X=0, 0.75Ni, 1.0Zn and 1.5In)/Cu solder joints during liquid aging
    Chen, Jie
    Shen, Jun
    Lai, Shiqiang
    Min, Dong
    Wang, Xiaochuan
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 489 (02) : 631 - 637
  • [3] Interaction behavior between the additives and Sn in Sn-3.0Ag-0.5Cu-based solder alloys and the relevant joint solderability
    Cheng, Fangjie
    Gao, Feng
    Nishikawa, Hiroshi
    Takemoto, Tadashi
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 472 (1-2) : 530 - 534
  • [4] Enhancement of heterogeneous nucleation of β-Sn phases in Sn-rich solders by adding minor alloying elements with hexagonal closed packed structures
    Cho, Moon Gi
    Kim, Hyun You
    Seo, Sun-Kyoung
    Lee, Hyuck Mo
    [J]. APPLIED PHYSICS LETTERS, 2009, 95 (02)
  • [5] Formation of Ag3Sn plates in SnAgCu solder bumps
    Gong, Jicheng
    Liu, Changqing
    Conway, Paul P.
    Silberschmidt, Vadim V.
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2010, 527 (10-11): : 2588 - 2591
  • [6] Formation of Sn dendrites and SnAg eutectics in a SnAgCu solder
    Gong, Jicheng
    Liu, Changqing
    Conway, Paul P.
    Silberschmidt, Vadim V.
    [J]. SCRIPTA MATERIALIA, 2009, 61 (07) : 682 - 685
  • [7] Ag3Sn plate formation in the solidification of near ternary eutectic Sn-Ag-Cu alloys
    Henderson, DW
    Gosselin, T
    Sarkhel, A
    Kang, SK
    Choi, WK
    Shih, DY
    Goldsmith, C
    Puttlitz, KJ
    [J]. JOURNAL OF MATERIALS RESEARCH, 2002, 17 (11) : 2775 - 2778
  • [8] HULTGREN R, 1990, SELECTIVE VALUES THE
  • [9] Ag3Sn plate formation in the solidification of near-ternary eutectic Sn-Ag-Cu
    Kang, SK
    Choi, WK
    Shih, DY
    Henderson, DW
    Gosselin, T
    Sarkhel, A
    Goldsmith, C
    Puttlitz, KJ
    [J]. JOM-JOURNAL OF THE MINERALS METALS & MATERIALS SOCIETY, 2003, 55 (06): : 61 - 65
  • [10] Controlling Ag3Sn plate formation, in near-ternary-eutectic Sn-Ag-Cu solder by minor Zn alloying
    Kang, SK
    Shih, DY
    Leonard, D
    Henderson, DW
    Gosselin, T
    Cho, SI
    Yu, J
    Choi, WK
    [J]. JOM, 2004, 56 (06) : 34 - 38