Twin structures of rhombohedral and cubic boron nitride prepared by chemical vapor deposition method

被引：75

作者：

Oku, T

Hiraga, K

Matsuda, T

Hirai, T

Hirabayashi, M

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan

[2] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan

[3] JMC New Mat Inc, Tokyo 1030013, Japan

[4] Japan Fine Ceram Ctr, Nagoya, Aichi 4568587, Japan

来源：

关键词：

rhombohedral boron nitride; twin structure; cubic boron nitride; transmission electron microscopy;

D O I：

10.1016/S0925-9635(02)00329-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanoparticles with a rhombohedral boron nitride (r-BN) structure were synthesized by a chemical vapor deposition method from BCl3-NH3-H-2 gas system at a temperature of 1600 degreesC and a total gas pressure of 3-5 Torr on the graphite substrates. The r-BN nanoparticles with the size of 50-1000 nm showed {101}, {113} and {001} twin structures. Cubic BN was also produced from r-BN under high pressure and high temperature, and {111} twin structure was observed. Electron diffraction patterns calculated based on the atomic structure models of these twin structures agreed well with the observations. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：1138 / 1145

页数：8

共 23 条

[1] STRUCTURAL FEATURES OF BORON-NITRIDE DENSE PHASE-FORMATION FROM RHOMBOHEDRAL MODIFICATION UNDER HIGH STATIC PRESSURE [J].