On the prebiotic potential of reduced oxidation state phosphorus: the H-phosphinate-pyruvate system

被引：23

作者：

Bryant, David E. ^{[1
]}

Marriott, Katie E. R. ^{[1
]}

Macgregor, Stuart A. ^{[2
]}

Kilner, Colin ^{[1
]}

Pasek, Matthew A. ^{[3
]}

Kee, Terence P. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Heriot Watt Univ, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland

[3] Univ S Florida, Dept Geol, Tampa, FL 33620 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 21期

基金：

英国工程与自然科学研究理事会;

关键词：

EARLY EARTH; IRON-METEORITES; REDOX CHEMISTRY; PHOSPHORYLATION; ORIGIN; LIFE; PHOSPHATES; CORROSION;

D O I：

10.1039/c002689a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

H-Phosphinic acid and pyruvic acid, both plausible prebiotic chemicals, react selectively in water to build structural complexity including amide bond formation under remarkably mild conditions and oxidative coupling of P(1) compounds to condensed pyrophosphorus compounds.

引用

页码：3726 / 3728

页数：3

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