Construction of the Oxazolidinone Framework from Propargylamine and CO2 in Air at Ambient Temperature: Catalytic Effect of a Gold Complex Featuring an L2/Z-Type Ligand

被引：28
作者：
Inagaki, Fuyuhiko [1 ]
Maeda, Kakeru [1 ]
Nakazawa, Kenta [1 ]
Mukai, Chisato [1 ]
机构：
[1] Kanazawa Univ, Grad Sch Med Sci, Div Pharmaceut Sci, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 23期
关键词：
Z-type ligands; Carboxylation; Carbon dioxide fixation; Gold; Heterocycles; DATIVE SIGMA-BOND; CARBON-DIOXIDE; CARBOXYLATION; ACID; REACTIVITY; PALLADIUM; AMINES; REARRANGEMENT; CYCLIZATION; ACTIVATION;
D O I：
10.1002/ejoc.201800228
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The metal-catalyzed carboxylation of propargylamines with aerial CO2 at room temperature to form 5-methyleneoxazolidin-2-one derivatives has been developed. In this reaction, the catalyst [Au(dpb(F))]X featuring a Z-type ligand gave the best results, presumably due to the sigma-acceptance of the borane atom.
引用
收藏
页码：2972 / 2976
页数：5
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