Dielectric and ferroelectric properties modification of 0.7Pb (Mg1/3Nb2/3)O3-0.3Pb(Zr0.52Ti0.48)O3 ceramics by Sa(Zn1/3Nb2/3)O3

被引:6
作者
Wattanasarn, Hassakorn [1 ,2 ]
Photankham, Wattana [1 ,2 ]
Seetawan, Tosawat [1 ,2 ]
Yimnirun, Rattikorn [3 ,4 ]
Thanachayanont, Chanchana [5 ]
Petnoi, Napatporn [6 ]
Pojprapai, Soodkhet [6 ]
机构
[1] Salon Nakhon Rajabhat Univ, Fac Sci & Technol, Program Phys, Ctr Excellence Alternat Energy, 680 Nittayo Rd, Sakon Nakhon 47000, Thailand
[2] Salon Nakhon Rajabhat Univ, Inst Res & Dev, 680 Nittayo Rd, Sakon Nakhon 47000, Thailand
[3] Suranaree Univ Technol, Inst Sci, Sch Phys, Nakhon Ratchasima 30000, Thailand
[4] Suranaree Univ Technol, COE NANOTEC SUT Adv Funct Nanomat, Nakhon Ratchasima 30000, Thailand
[5] Natl Sci & Technol Dev Agcy, Natl Met & Mat Technol Ctr, 114 Thailand Sci Pk,Phahonyothin Rd,Klong 1, Klongluang 12120, Pathumthani, Thailand
[6] Suranaree Univ Technol, Inst Engn, Sch Ceram Engn, Nakhon Ratchasima 30000, Thailand
关键词
Ceramics; Phase transitions; Microstructure; Dielectric properties; Ferroelectricity; ZIRCONATE-TITANATE CERAMICS; PHASE-TRANSFORMATION; PEROVSKITE; SYSTEM;
D O I
10.1016/j.materresbull.2015.11.047
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
(1 - x)[0.7Pb(Mg1/3Nb2/3)O-3-0.3Pb(Zr0.52Ti0.48)O-3]-xBa(Zn1/3Nb2/3)O-3 of which x = 0, 0.025, 0.05, 0.075, and 0.1 ceramics were studied by a composite powder method and using a two-step sintering process. The morphology showed that the largest grain size was about 1.866 mu m at x = 0.1, and the largest grain size of 3.81 mu m at x = 0.05. The 0.7PMN-0.3PZT showed a decreased dielectric constant, posed dispersive phase transition and indicated relaxor ferroelectric when modified by BZN contents. The polarization from hysteresis loop measurements showed that saturated polarization, remnant polarization and coercive field decreased with increasing BZN. Increasing BZN not only exhibits electrostrictive behaviors with linear hysteresis loop shape but it is also a good candidate for lower power energy application. The largest strain of 0.122% was found at x = 0.025. These results clearly demonstrated the significance of the 0.7PMN-0.3PZT system activated by BZN. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:292 / 299
页数:8
相关论文
共 26 条
[21]   Microwave dielectric properties of multi-ions Ba(Zn,Ta)O3-based perovskite ceramics [J].
Wang, Sea-Fue ;
Wang, Yuh-Ruey ;
Liu, Chung-Yu ;
Hsieh, Wen-Shuo .
CERAMICS INTERNATIONAL, 2012, 38 (02) :1127-1132
[22]   Effect of Ba(Zn1/3Nb2/3)O3 modification on structure and ferroelectric properties of 0.6Pb(Mg1/3Nb2/3)O3-0.4Pb(Zr0.52Ti0.48)O3 ceramics [J].
Wattanasarn, Hassakorn ;
Photankham, Wattana ;
Seetawan, Tosawat ;
Yimnirun, Rattikorn ;
Thanachayanont, Chanchana .
CERAMICS INTERNATIONAL, 2015, 41 (07) :8367-8376
[23]   Structural phase transformation and electrical properties of (0.90-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3-0.10Pb(Fe1/2Nb1/2)O3 ferroelectric ceramics near the morphotropic phase boundary [J].
Xia, Zhiguo ;
Li, Qiang .
ACTA MATERIALIA, 2007, 55 (18) :6176-6181
[24]   Phase transformation in (0.90-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3-0.1PbZrO3 piesoelectric ceramic:: X-ray diffraction and Raman investigation [J].
Xia, Zhiguo ;
Li, Qiang .
SOLID STATE COMMUNICATIONS, 2007, 142 (06) :323-328
[25]   Dielectric and ferroelectric properties of lead magnesium niobate-lead zirconate titanate ceramics prepared by mixed-oxide method [J].
Yimnirun, R ;
Ananta, S ;
Laoratanakul, P .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (13) :3235-3242
[26]   Effects of uniaxial stress on dielectric properties lead magnesium niobate-lead zirconate titanate ceramics [J].
Yimnirun, R ;
Ananta, S ;
Meechoowas, E ;
Wongsaenmai, S .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (13) :1615-1619