Synthesis, characterisation and flame retardance behaviour of poly(ethylene terephthalate) copolymer containing triaryl phosphine oxide

被引:84
作者
Wang, LS [1 ]
Wang, XL [1 ]
Yan, GL [1 ]
机构
[1] Beijing Inst Technol, Sch Chem Engn, Beijing 100081, Peoples R China
关键词
bis 4-Carboxyphenyl phenyl phosphine oxide; poly(ethylene terephthalate); flame retardant copolyester;
D O I
10.1016/S0141-3910(00)00050-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Bis 4-carboxyphenyl phenyl phosphine oxide (BCPPO) was prepared by oxidation of the corresponding dimethyl compound bis (4-methylphenyl) phenyl phosphine sulfide (prepared from the reaction of toluene with dichloro-phenyl phosphine sulfide). Flame resistant PET was prepared with BCPPO as a co-monomer. The resulting copolymers exhibit good fibre-forming properties, improved flame retarding behaviour, high glass transition temperatures and improved thermal stability. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:127 / 130
页数:4
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