Stabilization of tetrafluorobutatriene by complex formation

被引：16

作者：

Akkerman, Floris A. ^{[1
]}

Lentz, Dieter ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 26期

关键词：

pi complexes; carbonyl complexes; cumulenes; fluorine; transition metals;

D O I：

10.1002/anie.200701081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Now tamed: For decades preparative research on 1,1,4,4- tetrafluorobutatriene was not pursued because of the explosive nature of the compound. Two new transition-metal complexes containing a tetrafluorobutatriene ligand (see picture; green F/Cl, gray C, red O, purple P, orange Ir/Rh) have been prepared from the free triene, and both complexes are air-stable. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4902 / 4904

页数：3

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