COMPLEX SALT [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]•H2O AS A PROSPECTIVE PRECURSOR OF Pd-Rh NANOALLOYS. CRYSTAL STRUCTURE OF Na3[RhOx3]•4H2O

被引：5

作者：

Gladysheva, M., V ^{[1
,2
]}

Plyusnin, P. E. ^{[1
]}

Vorobyeva, S. N. ^{[1
]}

Komarov, V. Yu ^{[1
]}

Tkachev, S., V ^{[1
]}

Shubin, Yu, V ^{[1
]}

Korenev, S., V ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 62卷 / 05期

基金：

俄罗斯科学基金会;

关键词：

palladium; rhodium; complex salts; X-ray diffraction analysis; thermal analysis; nanoalloys; CATALYSTS; COORDINATION;

D O I：

10.1134/S0022476621050140

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New complex salts [Pd(NH3)(4)][Pd(NH3)(3)NO2][RhOx(3)]center dot H2O and Na-3[RhOx(3)]center dot 4H(2)O are prepared. The crystal structures of obtained compounds are determined by XRD. Complex salt [Pd(NH3)(4)] [Pd(NH3)(3)NO2][RhOx(3)]center dot H2O is studied by powder XRD, IR spectroscopy, and elemental analysis. The state of rhodium(III) in oxalate solutions is studied by NMR. Thermal behavior of [Pd(NH3)(4)][Pd(NH3)(3)NO2] [RhOx(3)]center dot H2O in various gas atmospheres shows that final thermolysis products in reducing and inert atmospheres are solid solutions Pd1-xRhx.

引用

页码：782 / 793

页数：12

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