Enhanced photocatalytic activity of molybdenum disulfide by compositing ZnAl-LDH

被引:35
作者
Chen, Shuang [1 ]
Yang, Fan [1 ]
Cao, Zhanfang [1 ]
Yu, Chao [1 ]
Wang, Shuai [1 ]
Zhong, Hong [1 ]
机构
[1] Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Efficient & Clean Utilizat Man, Changsha 410083, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Molybdenum disulfide; Hydrotalcite; Intercalation; Photocatalysis; LAYERED DOUBLE HYDROXIDE; WASTE-WATER; MECHANOCHEMICAL SYNTHESIS; OXYGEN EVOLUTION; DYE REMOVAL; HETEROJUNCTION; DEGRADATION; NANOCOMPOSITES; PERFORMANCE; ADSORPTION;
D O I
10.1016/j.colsurfa.2019.124140
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
MoS2 is a new type of two-dimensional material that can be used in the field of photocatalysis, but its agglomeration characteristics limit its use. So we tried to combine MoS2 with hydrotalcite to improve the morphology and enhance the performance of MoS2. The XRD, XPS, UV-vis prove that the material obtained is molybdenum disulfide intercalated zinc-aluminum hydrotalcite, and the SEM shows the particle size of molybdenum disulfide is reduced due to the interlaminar structure of hydrotalcite. Then, in the experiment of degrading methylene blue, the effects of cation ratio, thiourea dosage, pH and catalyst dosage on degradation were investigated. After 30 min of adsorption and 150 min of illumination, the maximum degradation rate of methylene blue can reach 93 %. And by analyzing the photocatalytic effect of the physical mixing of the two materials, it can be concluded that the photocatalytic performance of the composite material is better than that of the physical mixing of the two materials, which is close to 60 %. Therefore, composite with hydrotalcite enhances photocatalytic performance of MoS2, so the composite of MoS2/LDH has great potential in the field of photocatalytic degradation.
引用
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页数:10
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