Copper(II) cyanido-bridged bimetallic nitroprusside-based complexes: Syntheses, X-ray structures, magnetic properties, 57Fe Mossbauer spectroscopy and thermal studies

被引：14

作者：

Travnicek, Zdenek ^{[1
]}

Herchel, Radovan ^{[1
]}

Mikulik, Jiri ^{[1
]}

Zboril, Radek ^{[2
]}

机构：

[1] Palacky Univ, Fac Sci, Dept Inorgan Chem, CZ-77146 Olomouc, Czech Republic

[2] Palacky Univ, Fac Sci, Dept Phys Chem, CZ-77146 Olomouc, Czech Republic

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 05期

关键词：

Cyanido-bridged complex; Nitroprusside; Bimetallic complex; Copper spinel ferrite; POLYNUCLEAR COORDINATION-COMPOUNDS; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; FERRITE; DIFFRACTION; PRECURSORS; CUFE2O4; STATE; CU;

D O I：

10.1016/j.jssc.2010.03.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three heterobimetallic cyanido-bridged copper(II) nitroprusside-based complexes of the compositions [Cu(tet)Fe(CN)(5)O]center dot H2O (1), where tet=N,N'-bis(3-aminopropyl)ethylenediamine, [Cu(hto)Fe(CN)(5)NO]center dot 2H(2)O (2), where hto=1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(69)]octadecane and [Cu(hto)(2)Fe(CN)(5)NO]center dot H2O (3), where nme=N-methylethylenediamine, were synthesized and characterized by elemental analyses, Fe-57 Mossbauer and FTI spectroscopies, thermal analysis, magnetic measurements and single-crystal X-ray analysis. The products of thermal degradation processes of 2 and 3 were studied by XRD, Fe-57 Mossbauer spectroscopy, SEM and EDS, and they were identified as mixtures of CuFe2O4 and CuO. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：1046 / 1054

页数：9

共 55 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2]

[Anonymous], CRYSALIS RED CRYSALI

[3]

[Anonymous], 2014, SPECTROCHIM ACTA A, DOI DOI 10.1016/j.saa.2013.11.069

[4]

[Anonymous], 1971, M SSBAUER SPECTROSCO, DOI DOI 10.1007/978-94-009-5697-1

[5]

Baden-Fuller A.J., 1987, FERRITES MICROWAVE F

[6] Bimetallic cyanide-bridged complexes based on the photochromic nitroprusside anion and paramagnetic metal complexes [J].

Bellouard, F ;

Clemente-León, M ;

Coronado, E ;

Galán-Mascarós, JR ;

Giménez-Saiz, C ;

Gómez-García, CJ ;

Woike, T .

POLYHEDRON, 2001, 20 (11-14) :1615-1619

[7]

BOCA R, 2006, STRUCT BOND, V117, P172

[8]

Boca R., 1999, Theoretical Foundations of Molecular Magnetism

[9]

Brahmi R, 1998, STUD SURF SCI CATAL, V118, P403

[10]

Brandenburg K, DIAMOND CRYSTAL MOL

← 1 2 3 4 5 6 →