Synthesis and crystal structure of the aminoiminophosphinate copper(I) complex [Cu(Me3SiNP(Ph)2NSiMe3)]2

被引：0

作者：

Ackermann, H ^{[1
]}

Bock, O ^{[1
]}

Müller, U ^{[1
]}

Dehnicke, K ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 09期

关键词：

copper; aminoimino-phosphinate complex; crystal structure;

D O I：

10.1002/1521-3749(200009)626:9<1854::AID-ZAAC1854>3.0.CO;2-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound 1 was prepared by the reaction of Me3SiNP(Ph)(2)N(SiMe3)(2) with copper(I) chloride at 120 degrees C to give colourless crystals which were characterized by a crystal structure determination. Space group C2/c, Z = 4, lattice dimensions at 193 K: a = 1854.0(3). b = 1256.2(3), c = 1969.9(3)pm, beta = 106.30(2)degrees; R-1 = 0.063. 1 forms dimeric molecules with a nonplanar Cu2N4P2 eight-membered ring of symmetry C-2 and a rather long Cu ... Cu distance of 262.1(1) pm.

引用

页码：1854 / 1856

页数：3

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