Electrochemistry and electrochemiluminescence of copper metal cluster

被引：23

作者：

Han, Ailing ^{[1
]}

Yang, Yayu ^{[1
]}

Zhang, Qiang ^{[1
]}

Tu, Qingxia ^{[1
]}

Fang, Guozhen ^{[1
]}

Liu, Jifeng ^{[1
]}

Wang, Shuo ^{[1
]}

Li, Rui ^{[2
]}

机构：

[1] Tianjin Univ Sci & Technol, Key Lab Food Nutr & Safety, Minist Educ, Tianjin 300457, Peoples R China

[2] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2017年 / 795卷

关键词：

Electrochemistry; Electrochemiluminescence; Copper metal cluster; ELECTROGENERATED CHEMILUMINESCENCE; NANOCLUSTERS; LUMINESCENCE; FLUORESCENCE; ENHANCEMENT; PASSIVATION; LIGANDS; DENSITY;

D O I：

10.1016/j.jelechem.2017.04.058

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemistry and electrochemiluminescence (ECL) of copper metal cluster were studied in this work. The redox behavior observed was originated from the couples of Cu-8(+)/Cu-8(2+) Cus/Cu-8(2+), Cu-8/Cu-8(+) at the cluster metal core. ECL light emissions were observed under both annihilation and tripropylamine co-reactant conditions and only one excited state was involved in this ECL process and this excited state was also at the metal core. Theoretical investigation found that this excitation corresponds to an electron transfer from the metal core to the ligands. And the energy released from excited sate was approximate to the LUMO -> HOMO gap energy of the cluster.

引用

页码：116 / 122

页数：7

共 36 条

[1]

Armirotti A., 2015, ACS NANO, V9, P11886

[2] Copper nanocluster coupling europium as an off-to-on fluorescence probe for the determination of phosphate ion in water samples [J].

Cao, Haiyan ;

Chen, Zhaohui ;

Huang, Yuming .

TALANTA, 2015, 143 :450-456

[3] Long-range corrected hybrid density functionals with damped atom-atom dispersion corrections [J].

Chai, Jeng-Da ;

Head-Gordon, Martin .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (44) :6615-6620

[4] Size-tunable copper nanocluster aggregates and their application in hydrogen sulfide sensing on paper-based devices [J].

Chen, Po-Cheng ;

Li, Yu-Chi ;

Ma, Jia-Yin ;

Huang, Jia-Yu ;

Chen, Chien-Fu ;

Chang, Huan-Tsung .

SCIENTIFIC REPORTS, 2016, 6

[5] Photoemission Mechanism of Water-Soluble Silver Nanoclusters: Ligand-to-Metal-Metal Charge Transfer vs Strong Coupling between Surface Plasmon and Emitters [J].

Chen, Yuting ;

Yang, Taiqun ;

Pan, Haifeng ;

Yuan, Yufeng ;

Chen, Li ;

Liu, Mengwei ;

Zhang, Kun ;

Zhang, Sanjun ;

Wu, Peng ;

Xu, Jianhua .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (05) :1686-1689

[6] Theoretical Insights into the Origin of Photoluminescence of Au25(SR)18- Nanoparticles [J].

Dimuthu, K. L. ;

Weerawardene, M. ;

Aikens, Christine M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (35) :11202-11210

[7] Electrochemistry and electrogenerated chemiluminescence from silicon nanocrystal quantum dots [J].

Ding, ZF ;

Quinn, BM ;

Haram, SK ;

Pell, LE ;

Korgel, BA ;

Bard, AJ .

SCIENCE, 2002, 296 (5571) :1293-1297

[8]

Frisch M.J., 2016, Gaussian, V16

[9] Sub-nanometer sized Cu6(GSH)3 clusters: one-step synthesis and electrochemical detection of glucose [J].

Gao, Xiaohui ;

Lu, Yizhong ;

Liu, Minmin ;

He, Shuijian ;

Chen, Wei .

JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (16) :4050-4056

[10] Copper nanocluster-based fluorescent sensors for sensitive and selective detection of kojic acid in food stuff [J].

Gao, Zhao ;

Su, Rongxin ;

Qi, Wei ;

Wang, Libing ;

He, Zhimin .

SENSORS AND ACTUATORS B-CHEMICAL, 2014, 195 :359-364

← 1 2 3 4 →