Electrogenerated Sm(II)-Catalyzed CO2 Activation for Carboxylation of Benzyl Halides

被引：60
作者：
Bazzi, Sakna [1 ]
Schulz, Emmanuelle [1 ]
Mellah, Mohamed [1 ]
机构：
[1] Univ Paris Saclay, Univ Paris Sud, Inst Chim Mol & Mat Orsay, Equipe Catalyse Mol,CNRS,UMR 8182, 15 Rue Georges Clemenceau, F-91405 Orsay, France
来源：
ORGANIC LETTERS | 2019年 / 21卷 / 24期
关键词：
FUNCTIONALIZED ORGANOZINC REAGENTS; CARBON-DIOXIDE; CATALYZED CARBOXYLATION; ELECTROCARBOXYLATION; TRANSFORMATION; DERIVATIVES; ALDEHYDES; KETONES; ACIDS;
D O I：
10.1021/acs.orglett.9b03927
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sm(II)-catalyzed carboxylation of benzyl halides is reported through the electrochemical reduction of CO2. The transformation proceeds under mild reaction conditions to afford the corresponding phenylacetic acids in good to excellent yields. This user-friendly and operationally simple protocol represents an alternative to traditional strategies, which usually proceeds through the C(sp(3))-halide activation pathway.
引用
收藏
页码：10033 / 10037
页数：5
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